The Natural Mineral Water, Spring Water and Bottled Drinking Water (Scotland) Regulations 2007
Made: 20th September 2007
Laid before the Scottish Parliament: 21st September 2007
Coming into force: 31st October 2007
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PART 1 — Introductory
Citation, commencement and extent
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Interpretation
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Exemptions
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PART 2 — Natural mineral water
Recognition as natural mineral water
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Exploitation of natural mineral water springs
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Treatments and additions for natural mineral water
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Bottling of natural mineral water
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Marking, labelling and advertisement of natural mineral waters
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Sale of natural mineral water
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PART 3 — Spring water
Bottling of spring water and exploitation of spring water springs
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Marking, labelling and advertisement of spring water
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Sale of spring water
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PART 4 — Bottled drinking water
Bottling of drinking water
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Marking, labelling and advertising of bottled drinking water
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Sale of bottled drinking water
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PART 5 — Miscellaneous and supplemental
Enforcement
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Arrangements for samples taken for analysis
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Submission of samples to the Government Chemist
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Methods of analysis
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Offences and penalties
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Defences
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Application of other provisions
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Revocations
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SCHEDULE 1 — Conditions for treatment of natural mineral waters and spring waters with ozone-enriched air
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SCHEDULE 2 — Requirements for spring water and drinking water including prescribed concentrations or values of parameters
PART 1 — Requirements for spring water and drinking water
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PART 2 — Prescribed concentrations or values
| Column 1 | Column 2 | Column 3 | Column 4 |
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| Item | Parameters | Units of Measurement | Concentration or Value (maximum unless otherwise stated) |
| Notes: The concentration (mg/l) of nitrate divided by 50 added to the concentration (mg/l) of nitrite divided by 3 must not exceed 1. Excluding tritium, potassium 40, radon and radon decay products. | Notes: The concentration (mg/l) of nitrate divided by 50 added to the concentration (mg/l) of nitrite divided by 3 must not exceed 1. Excluding tritium, potassium 40, radon and radon decay products. | Notes: The concentration (mg/l) of nitrate divided by 50 added to the concentration (mg/l) of nitrite divided by 3 must not exceed 1. Excluding tritium, potassium 40, radon and radon decay products. | Notes: The concentration (mg/l) of nitrate divided by 50 added to the concentration (mg/l) of nitrite divided by 3 must not exceed 1. Excluding tritium, potassium 40, radon and radon decay products. |
| 1. | Colour | mg/1 Pt/Co scale | 20 |
| 2. | Turbidity | NTU | 4 |
| 3. | Odour | Dilution number | 3 at 25°C |
| 4. | Taste | Dilution number | 3 at 25°C |
| 5. | Sulphate | mg SO₄/1 | 250 |
| 6. | Sodium | mg Na/l | 200 |
| 7. | Nitrate | mg NO₃/l | 50 (note 1) |
| 8. | Nitrite | mg NO₂/l | 0.5 (note 1) |
| 9. | Aluminium | μgAl/l | 200 |
| 10. | Copper | mg Cu/l | 2 |
| 11. | Fluoride | mg F/l | 1.5 |
| 12. | Hydrogen ion concentration | pH units | 4.5 (minimum) 9.5 (maximum) |
| 13. | Tritium (for radioactivity) | Bq/l | 100 |
| 14. | Total indicative dose | mSv/year | 0.10 (note 2) |
| 15. | Manganese | μg Mn/l | 50 |
| Column 1 | Column 2 | Column 3 | Column 4 |
| --- | --- | --- | --- |
| Item | Parameters | Units of Measurement | Maximum Concentration |
| Notes: Pesticides” means: organic insecticides, organic herbicides, organic fungicides, organic nematocides, organic acaricides, organic algicides, organic rodenticides, organic slimicides, and related products (inter alia, growth regulators) and their relevant metabolites, degradation and reaction products. Only those pesticides which are likely to be present in a given water need to be monitored. The maximum concentration applies to each individual pesticide. In the case of aldrin, dieldrin, heptaclor and heptachlor epoxide the maximum concentration is 0.030 μg/l. The maximum concentration for “total substances” refers to the sum of the concentrations of all individual pesticides detected and quantified in the monitoring procedure. The specified compounds are benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(ghi)perylene, indeno(1.2,3 cd) pyrene. | Notes: Pesticides” means: organic insecticides, organic herbicides, organic fungicides, organic nematocides, organic acaricides, organic algicides, organic rodenticides, organic slimicides, and related products (inter alia, growth regulators) and their relevant metabolites, degradation and reaction products. Only those pesticides which are likely to be present in a given water need to be monitored. The maximum concentration applies to each individual pesticide. In the case of aldrin, dieldrin, heptaclor and heptachlor epoxide the maximum concentration is 0.030 μg/l. The maximum concentration for “total substances” refers to the sum of the concentrations of all individual pesticides detected and quantified in the monitoring procedure. The specified compounds are benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(ghi)perylene, indeno(1.2,3 cd) pyrene. | Notes: Pesticides” means: organic insecticides, organic herbicides, organic fungicides, organic nematocides, organic acaricides, organic algicides, organic rodenticides, organic slimicides, and related products (inter alia, growth regulators) and their relevant metabolites, degradation and reaction products. Only those pesticides which are likely to be present in a given water need to be monitored. The maximum concentration applies to each individual pesticide. In the case of aldrin, dieldrin, heptaclor and heptachlor epoxide the maximum concentration is 0.030 μg/l. The maximum concentration for “total substances” refers to the sum of the concentrations of all individual pesticides detected and quantified in the monitoring procedure. The specified compounds are benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(ghi)perylene, indeno(1.2,3 cd) pyrene. | Notes: Pesticides” means: organic insecticides, organic herbicides, organic fungicides, organic nematocides, organic acaricides, organic algicides, organic rodenticides, organic slimicides, and related products (inter alia, growth regulators) and their relevant metabolites, degradation and reaction products. Only those pesticides which are likely to be present in a given water need to be monitored. The maximum concentration applies to each individual pesticide. In the case of aldrin, dieldrin, heptaclor and heptachlor epoxide the maximum concentration is 0.030 μg/l. The maximum concentration for “total substances” refers to the sum of the concentrations of all individual pesticides detected and quantified in the monitoring procedure. The specified compounds are benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(ghi)perylene, indeno(1.2,3 cd) pyrene. |
| 1. | Arsenic | μg As/l | 10 |
| 2. | Cadmium | μg Cd/l | 5 |
| 3. | Cyanide | μg CN/l | 50 |
| 4. | Chromium | μg Cr/l | 50 |
| 5. | Mercury | μg Hg/l | 1 |
| 6. | Nickel | μg Ni/l | 20 |
| 7. | Selenium | μg Se/l | 10 |
| 8. | Antimony | μg Sb/l | 5 |
| 9. | Lead | μg Pb/l | 10 |
| 10. | Pesticides and related products: | ||
| – individual substances | μg/l | 0.10 (notes 1 and 2) | |
| – total substances | μg/l | 0.50 (notes 1 and 3) | |
| 11. | Polycyclic aromatic Hydrocarbons | μg/l | 0.1 sum of concentrations of specified compounds (note 4) |
| 12. | Bromate | μg BrO₃/l | 10 |
| Column 1 | Column 2 | Column 3 | Column 4 |
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| Item | Parameters | Units of Measurement | Maximum Concentration |
| Notes: The total viable colony count should be measured within 12 hours of bottling, with the sample water being kept at a constant temperature during that 12 hour period. Any increase in the total viable colony count of the water between 12 hours after bottling and the time of sale should not be greater than that normally expected. In 72 hours on agar-agar or an agar-gelatine mixture. In 24 hours on agar-agar. | Notes: The total viable colony count should be measured within 12 hours of bottling, with the sample water being kept at a constant temperature during that 12 hour period. Any increase in the total viable colony count of the water between 12 hours after bottling and the time of sale should not be greater than that normally expected. In 72 hours on agar-agar or an agar-gelatine mixture. In 24 hours on agar-agar. | Notes: The total viable colony count should be measured within 12 hours of bottling, with the sample water being kept at a constant temperature during that 12 hour period. Any increase in the total viable colony count of the water between 12 hours after bottling and the time of sale should not be greater than that normally expected. In 72 hours on agar-agar or an agar-gelatine mixture. In 24 hours on agar-agar. | Notes: The total viable colony count should be measured within 12 hours of bottling, with the sample water being kept at a constant temperature during that 12 hour period. Any increase in the total viable colony count of the water between 12 hours after bottling and the time of sale should not be greater than that normally expected. In 72 hours on agar-agar or an agar-gelatine mixture. In 24 hours on agar-agar. |
| 1. | Escherichia coli (E.coli) | number/250 ml | 0/250 ml |
| 2. | Enterococci | number/250 ml | 0/250 ml |
| 3. | Colony count 22°C | number/ml | 100/ml (notes 1 and 2) |
| 4. | Colony count 37°C | number/ml | 20/ml (notes 1 and 3) |
| 5. | Pseudomonas aeruginosa | number/250/ml | 0/250 ml |
| Column 1 | Column 2 | Column 3 | Column 4 |
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| Item | Parameters | Unit of Measurements | Maximum Concentration |
| Notes: The maximum concentration specified applies to the sum of the concentrations of the specified parameters. The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. | Notes: The maximum concentration specified applies to the sum of the concentrations of the specified parameters. The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. | Notes: The maximum concentration specified applies to the sum of the concentrations of the specified parameters. The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. | Notes: The maximum concentration specified applies to the sum of the concentrations of the specified parameters. The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. |
| 1. | Boron | Mg B/l | 1.0 |
| 2. | Benzo (a) pyrene | μg/l | 0.010 |
| 3. | Tetrachloroethene and Trichloroethene | μg/l | 10 (note 1) |
| 4. | Tetrachloromethane | μg/l | 3 |
| 5. | Benzene | μg/l | 1.0 |
| 6. | 1,2-dichloroethane | μg/l | 3.0 |
| 7. | Trichloromethane, Dichlororbromomethane, Dibromochloromethane and Tribromomethane | μg/l | 100 (note 1) |
| 8. | Epichlorohydrin | μg/l | 0.10 (note 2) |
| 9. | Vinyl chloride | μg/l | 0.50 (note 2) |
| 10. | Acrylamide | μg/l | 0.10 (note 2) |
SCHEDULE 3 — Recognition of natural mineral waters
PART 1 — Natural mineral waters extracted from the ground in Scotland
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PART 2 — Natural mineral waters extracted from the ground in a country other than an EEA State
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PART 3 — Requirements and criteria for recognition as a natural mineral water
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SCHEDULE 4 — Exploitation and bottling requirements for natural mineral water and spring water
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SCHEDULE 5 — Particulars of anions, cations, non-ionised compounds and trace elements
| Anions | Unit of measurement |
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| Borate BO₃− | mg/1 |
| Carbonate CO₃2− | mg/1 |
| Chloride Cl− | mg/1 |
| Fluoride F− | mg/l |
| Hydrogen Carbonate HCO₃− | mg/1 |
| Nitrate NO₃− | mg/1 |
| Nitrite NO₂− | mg/1 |
| Phosphate PO₄3− | mg/1 |
| Silicate SiO₂ | mg/1 |
| Sulphate SO₄2− | mg/1 |
| Sulphide S2− | mg/1 |
| Cations | Unit of measurement |
| Aluminium A1 | mg/1 |
| Ammonium NH₄⁺ | mg/1 |
| Calcium Ca | mg/1 |
| Magnesium Mg | mg/1 |
| Potassium K | mg/l |
| Sodium Na | mg/1 |
| Non-ionised compounds | Unit of measurement |
| Total organic carbon C | mg/1 |
| Free carbon dioxide CO₂ | mg/1 |
| Silica SiO₂ | mg/1 |
| Trace elements | Unit of measurement |
| Barium Ba | μg/l |
| Bromine (total) Br | μg/l |
| Cobalt Co | μg/l |
| Copper Cu | μg/l |
| Iodine (total) I | μg/l |
| Iron Fe | μg/l |
| Lithium Li | μg/l |
| Manganese Mn | μg/l |
| Molybdenum Mo | μg/l |
| Strontium Sr | μg/l |
| Zinc Zn | μg/1 |
SCHEDULE 6 — Maximum limits for constituents of natural mineral waters
| Constituents | Maximum limits (mg/l) |
|---|---|
| Note: The constituents described above refer to constituents naturally present in the water at source and not to substances present as the result of contamination. | Note: The constituents described above refer to constituents naturally present in the water at source and not to substances present as the result of contamination. |
| Antimony | 0.0050 |
| Arsenic | 0.010 (as total) |
| Barium | 1.0 |
| Cadmium | 0.003 |
| Chromium | 0.050 |
| Copper | 1.0 |
| Cyanide | 0.070 |
| Fluoride | 5.0 |
| Lead | 0.010 |
| Manganese | 0.50 |
| Mercury | 0.0010 |
| Nickel | 0.020 |
| Nitrate | 50.0 |
| Nitrite | 0.1 |
| Selenium | 0.010 |
SCHEDULE 7 — Performance characteristics for analysing the constituents in Schedule 6
| Constituent | Accuracy of parametric value in % | Precision of parametric value | Detection limit of parametric value in % |
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| Notes: The method of analysis used to measure the concentration of the constituents in Schedule 6 shall be able to measure at least concentrations equal to the parametric value with the specified accuracy, precision and detection limits. Regardless of the sensitivity of the method of analysis, the result must be expressed to the same number of decimal places as the maximum limit set out in Schedule 6 for the particular constituent being analysed. Accuracy is the systematic error and represents the difference between the average value of a large number of repeated measurements and the exact value. Precision represents the random error and is expressed in general as the standard deviation (within a batch and between batches) of a sample of results from the average. Acceptable precision is equal to twice the relative standard deviation. The detection limit is– three times the relative standard deviation within a batch of a natural sample containing a low concentration of the constituent; or five times the relative standard deviation within a batch of a virgin sample. The method should make it possible to determine total cyanide in all its forms. | Notes: The method of analysis used to measure the concentration of the constituents in Schedule 6 shall be able to measure at least concentrations equal to the parametric value with the specified accuracy, precision and detection limits. Regardless of the sensitivity of the method of analysis, the result must be expressed to the same number of decimal places as the maximum limit set out in Schedule 6 for the particular constituent being analysed. Accuracy is the systematic error and represents the difference between the average value of a large number of repeated measurements and the exact value. Precision represents the random error and is expressed in general as the standard deviation (within a batch and between batches) of a sample of results from the average. Acceptable precision is equal to twice the relative standard deviation. The detection limit is– three times the relative standard deviation within a batch of a natural sample containing a low concentration of the constituent; or five times the relative standard deviation within a batch of a virgin sample. The method should make it possible to determine total cyanide in all its forms. | Notes: The method of analysis used to measure the concentration of the constituents in Schedule 6 shall be able to measure at least concentrations equal to the parametric value with the specified accuracy, precision and detection limits. Regardless of the sensitivity of the method of analysis, the result must be expressed to the same number of decimal places as the maximum limit set out in Schedule 6 for the particular constituent being analysed. Accuracy is the systematic error and represents the difference between the average value of a large number of repeated measurements and the exact value. Precision represents the random error and is expressed in general as the standard deviation (within a batch and between batches) of a sample of results from the average. Acceptable precision is equal to twice the relative standard deviation. The detection limit is– three times the relative standard deviation within a batch of a natural sample containing a low concentration of the constituent; or five times the relative standard deviation within a batch of a virgin sample. The method should make it possible to determine total cyanide in all its forms. | Notes: The method of analysis used to measure the concentration of the constituents in Schedule 6 shall be able to measure at least concentrations equal to the parametric value with the specified accuracy, precision and detection limits. Regardless of the sensitivity of the method of analysis, the result must be expressed to the same number of decimal places as the maximum limit set out in Schedule 6 for the particular constituent being analysed. Accuracy is the systematic error and represents the difference between the average value of a large number of repeated measurements and the exact value. Precision represents the random error and is expressed in general as the standard deviation (within a batch and between batches) of a sample of results from the average. Acceptable precision is equal to twice the relative standard deviation. The detection limit is– three times the relative standard deviation within a batch of a natural sample containing a low concentration of the constituent; or five times the relative standard deviation within a batch of a virgin sample. The method should make it possible to determine total cyanide in all its forms. |
| Antimony | 25 | 25 | 25 |
| Arsenic | 10 | 10 | 10 |
| Barium | 25 | 25 | 25 |
| Cadmium | 10 | 10 | 10 |
| Chromium | 10 | 10 | 10 |
| Copper | 10 | 10 | 10 |
| Cyanide | 10 | 10 | 10 |
| Fluoride | 10 | 10 | 10 |
| Lead | 10 | 10 | 10 |
| Manganese | 10 | 10 | 10 |
| Mercury | 20 | 10 | 20 |
| Nickel | 10 | 10 | 10 |
| Nitrate | 10 | 10 | 10 |
| Nitrite | 10 | 10 | 10 |
| Selenium | 10 | 10 | 10 |
SCHEDULE 8 — Labelling indications for natural mineral water and criteria for use
| Indication | Criteria |
|---|---|
| Low mineral content | Mineral salt content, calculated as a fixed residue, not greater than 500 mg/l |
| Very low mineral content | Mineral salt content, calculated as a fixed residue, not greater than 50 mg/l |
| Rich in mineral salts | Mineral salt content, calculated as a fixed residue, greater than 1500 mg/l |
| Contains bicarbonate | Bicarbonate content greater than 600 mg/l |
| Contains sulphate | Sulphate content greater than 200 mg/l |
| Contains chloride | Chloride content greater than 200 mg/l |
| Contains calcium | Calcium content greater than 150 mg/l |
| Contains magnesium | Magnesium content greater than 50 mg/l |
| Contains fluoride | Fluoride content greater than 1 mg/l |
| Contains iron | Bivalent iron content greater than 1 mg/l |
| Acidic | Free carbon dioxide content greater than 250 mg/l |
| Contains sodium | Sodium content greater than 200 mg/l |
| Suitable for a low-sodium diet | Sodium content less than 20 mg/l |
Signed
SHONA ROBISON — Authorised to sign by the Scottish Ministers — 20th September 2007
Explanatory note
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Footnotes
[^f00001]: 1990 c. 16; section 1(1) and (2) (definition of “food”) was substituted by S.I. 2004/2990; section 6(4) was amended by the Deregulation and Contracting Out Act 1994 (c. 40), Schedule 9, paragraph 6 and by the Food Standards Act 1999 (c. 28) (“the 1999 Act”), Schedule 5, paragraph 10(3); section 17(1) and (2) was amended by the 1999 Act, Schedule 5, paragraphs 8 and 12; section 26(3) was amended by the 1999 Act, Schedule 6; section 48(1) was amended by the 1999 Act, Schedule 5, paragraph 8; section 48(4) is disapplied in respect of these Regulations by virtue of section 48(4C) which was inserted by S.I. 2004/2990; amendments made by Schedule 5 to the 1999 Act shall be taken as pre-commencement enactments for the purposes of the Scotland Act 1998 (c. 46) (“the 1998 Act”) by virtue of section 40(2) of the 1999 Act. The functions of the Secretary of State, in so far as within devolved competence, were transferred to the Scottish Ministers by virtue of section 53 of the 1998 Act. In so far as not so transferred, those functions were transferred to the Scottish Ministers by the Scotland Act 1998 (Transfer of Functions to the Scottish Ministers etc.) Order 2005 (S.I. 2005/849).
[^f00002]: Section 48(4A) was inserted by paragraph 21 of Schedule 5 to the 1999 Act.
[^f00003]: O.J. No. L 31, 1.2.02, p.1 as last amended by Regulation (EC) No. 1642/2003 of the European Parliament and of the Council (O.J. No. L 245, 29.9.03, p.4).
[^f00004]: S.I. 1996/1499, to which there are amendments not relevant to these Regulations.
[^f00005]: O.J. No. L 229, 30.8.80, p.1.
[^f00006]: O.J. No. L 299, 23.11.96, p.26.
[^f00007]: O.J. No. L 330, 5.12.98, p.32.
[^f00008]: O.J. No. L 111, 20.4.01, p.31.
[^f00009]: O.J. No. L 126, 22.5.03, p.34.
[^f00010]: 1968 c. 67.
[^f00011]: S.I. 1994/3144; to which there are amendments not relevant to these Regulations.
[^f00013]: S.I. 1985/71, revoked by S.S.I. 1999/1540.
[^f00014]: S.I. 1999/1540, as amended by S.S.I. 2000/62; S.S.I. 2003/139 and S.S.I. 2004/132.
[^f00015]: S.I. 1999/1540, amended by S.S.I. 2000/62, 2003/139, 2004/132 and 2005/616.
[^f00016]: S.I. 1996/1499; to which there are amendments not relevant to these Regulations.
[^f00017]: S.S.I. 2003/139.
[^f00018]: S.S.I. 2004/132.
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