LegalizeThe Chemicals (Hazard Information and Packaging for Supply) (Amendment) (No. 3) Regulations 1999
Made: 29th November 1999
Laid before Parliament: 30th November 1999
Coming into force: 4th January 2000
The Secretary of State, being the designated Minister for the purpose of section 2(2) of the European Communities Act 1972 in relation to the regulation and control of classification, packaging and labelling of dangerous substances and preparations, and for measures related to consumer protection, in the exercise of the powers conferred on him by the said section 2(2) hereby makes the following Regulations:—
1
These Regulations may be cited as the Chemicals (Hazard Information and Packaging for Supply) (Amendment) (No. 3) Regulations 1999 and shall come into force on 4th January 2000.
2
The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994 are amended by substituting for Part III of Schedule 6 the contents of the Schedule to these Regulations.
SCHEDULE — NEW PART III OF SCHEDULE 6 TO THE PRINCIPAL REGULATIONS
PART III — SUBSTANCES REQUIRING ADDITIONAL LABELLING PHRASE A
- Category 1 and 2 Carcinogenic, Mutagenic and Toxic for Reproduction substances requiring additional labelling phrase
- The substances referred to in regulation 9(3A) are specified in the table below
Carcinogenic substance of Category 1
| Substances | Index Number | EC number | CAS number | Notes |
|---|---|---|---|---|
| Chromium trioxide | 024-001-00-0 | 215-607-8 | 1333-82-0 | |
| Zinc chromates including zinc potassium chromate | 024-007-00-3 | |||
| nickel monoxide | 028-003-00-2 | 215-215-7 | 1313-99-1 | |
| nickel dioxide | 028-004-00-8 | 234-823-3 | 12035-36-8 | |
| dinickel trioxide | 028-005-00-3 | 215-217-8 | 1314-06-3 | |
| nickel sulphide | 028-006-00-9 | 240-841-2 | 16812-54-7 | |
| nickel subsulphide | 028-007-00-4 | 234-829-6 | 12035-72-2 | |
| diarsenic trioxide; arsenic trioxide | 033-003-00-0 | 215-481-4 | 1327-53-3 | |
| arsenic pentoxide; arsenic oxide | 033-004-00-6 | 215-116-9 | 1303-28-2 | |
| arsenic acid and its salts | 033-005-00-1 | |||
| lead hydrogen arsenate | 082-011-00-0 | 232-064-2 | 7784-40-9 | |
| benzene | 601-020-00-8 | 200-753-7 | 71-43-2 | |
| vinyl chloride; chloroethylene | 602-023-00-7 | 200-831-0 | 75-01-4 | |
| Bis (chloromethyl) ether | 603-046-00-5 | 208-832-8 | 542-88-1 | |
| Chloromethyl methyl ether; chlorodimethyl ether | 603-075-00-3 | 203-408-1 | 107-30-2 | |
| 2-naphthylamine; beta-naphthylamine | 612-022-00-3 | 202-080-4 | 91-59-8 | |
| benzidine; 4,4'-diaminobiphenyl; biphenyl-4,4'-ylenediamine | 612-042-00-2 | 202-199-1 | 92-87-5 | |
| salts of benzidine | 612-070-00-5 | |||
| salts of 2-naphthylamine | 612-071-00-0 | |||
| biphenyl-4-ylamine; xenylamine; 4-aminobiphenyl | 612-072-00-6 | 202-177-1 | 92-67-1 | |
| salts of biphenyl-4-ylamine; salts of xenylamine; salts of 4-aminobiphenyl | 612-073-00-1 | |||
| Tar, coal; coal tar (The by-product from the destructive distillation of coal. Almost black semisolid. A complex combination of aromatic hydrocarbons, phenolic compounds, nitrogen bases and thiophene.) | 648-081-00-7 | 232-361-7 | 8007-45-2 | |
| Tar, coal, high-temp.; Coal tar (The condensation product obtained by cooling, to approximately ambient temperature, the gas evolved in the high temperature (greater than 700°C (1292°F)) destructive distillation of coal. A black viscous liquid denser than water. Composed primarily of a complex mixture of condensed ring aromatic hydrocarbons. May contain minor amounts of phenolic compounds and aromatic nitrogen bases.) | 648-082-00-2 | 266-024-0 | 65996-89-6 | |
| Tar, coal, low-temp.; Coal oil (The condensation product obtained by cooling, to approximately ambient temperature, the gas evolved in low temperature (less than 700°C (1292°F)) destructive distillation of coal. A black viscous liquid denser than water. Composed primarily of condensed ring aromatic hydrocarbons, phenolic compounds, aromatic nitrogen bases, and their alkyl derivatives.) | 648-083-00-8 | 266-025-6 | 65996-90-9 | |
| Tar brown-coal; (An oil distilled from brown-coal tar. Composed primarily of aliphatic, naphthenic and one-to three-ring aromatic hydrocarbons, their alkyl derivatives, heteroaromatics and one-and two-ring phenols boiling in the range of approximately 150°C to 360°C (302°F to 680°F).) | 648-145-00-4 | 309-885-0 | 101316-83-0 | |
| Tar, brown-coal, low temp; (A tar obtained from low temperature carbonization and low temperature gasification of brown coal. Composed primarily of aliphatic, naphthenic and cyclic aromatic hydrocarbons, heteroaromatic hydrocarbons and cyclic phenols.) | 648-146-00-X | 309-886-6 | 101316-84-1 | |
| Coke (coal tar), high temperature pitch | 648-157-00-X | 140203-12-9 | ||
| Coke (coal tar), mixed coal-high temperature pitch | 648-158-00-5 | 140203-13-0 | ||
| Coke (coal tar) low temperature, high temperature pitch | 648-159-00-0 | 140413-61-2 | ||
| Distillates (petroleum), light paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀ and produces a finished oil with a viscosity of less than 100 SUS at 100°F (19 cS at 40°C). It contains a relatively large proportion of saturated aliphatic hydrocarbons normally present in this distillation range of crude oil.) | 649-050-00-0 | 265-051-5 | 64741-50-0 | |
| Distillates (petroleum), heavy paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains a relatively large proportion of saturated aliphatic hydrocarbons.) | 649-051-00-6 | 265-052-0 | 64741-51-1 | |
| Distillates (petroleum), light naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-052-00-1 | 265-053-6 | 64741-52-2 | |
| Distillates (petroleum), heavy naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-053-00-7 | 265-054-1 | 64741-53-3 | |
| Distillates (petroleum), acid-treated heavy naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid treating process. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-054-00-2 | 265-117-3 | 64742-18-3 | |
| Distillates (petroleum), acid-treated light naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid treating process. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-055-00-8 | 265-118-9 | 64742-19-4 | |
| Distillates (petroleum), acid-treated heavy paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid process. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C).) | 649-056-00-3 | 265-119-4 | 64742-20-7 | |
| Distillates (petroleum), acid-treated light paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid treating process. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C).) | 649-057-00-9 | 265-121-5 | 64742-21-8 | |
| Distillates (petroleum), chemically neutralized heavy paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained from a treating process to remove acidic materials. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains a relatively large proportion of aliphatic hydrocarbons.) | 649-058-00-4 | 265-127-8 | 64742-27-4 | |
| Distillates (petroleum), chemically neutralized light paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by a treating process to remove acidic materials. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with viscosity of at least 100 SUS at 100°F (19 cSt at 40°C).) | 649-059-00-X | 265-128-3 | 64742-28-5 | |
| Distillates (petroleum), chemically neutralized heavy naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by a treating process to remove acidic materials. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-060-00-5 | 265-135-1 | 64742-34-3 | |
| Distillates (petroleum), chemically neutralized light napthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by a treating process to remove acidic materials. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-061-00-0 | 265-136-7 | 64742-35-4 | |
| erionite | 650-012-00-0 | 12510-42-8 | ||
| asbestos | 650-013-00-6 | 132207-33-1 132207-32-0 12172-73-5 77536-66-4 77536-68-6 77536-67-5 |
Carcinogenic substances of Category 2
Mutagenic substances of Category 2
Toxic for reproduction substances of Category 1
Toxic for reproduction substances of Category 2
Note
The index number is the identification code given to the substance in Annex 1 of Directive 67/548/EEC. Substances are listed in the Schedule according to this index number.
The EC number for each substance listed in the European Inventory of Existing Commercial Chemical Substances (Einecs) there is an identification code which starts at 200-001-8. For each new substance notified under the Directive 67/548/EEC an idenfication code has been defined and published in the European List of Notified Chemical Substances (Elincs). The code starts at 400-010-9.
The CAS number is the number assigned to the substance by the “Chemicals Abstract Service”.
Signed
Kim Howells, — Parliamentary Under-Secretary of State for Consumers and Corporate Affairs, — Department of Trade and Industry — 29th November 1999
Explanatory note
(This note is not part of the Regulations)
Footnotes
[^f00001]: S.I. 1976/897 and 1993/2661.
[^f00002]: S.I. 1972 c. 68.
[^f00003]: S.I. 1994/3247, amended by S.I. 1996/1092 which inserted Part III of Schedule 6. The 1994 Regulations have also been amended by S.I. 1999/197 and S.I. 1999/3165 in a manner not relevant to these Regulations.
Category 1 and 2 Carcinogenic, Mutagenic and Toxic for Reproduction substances requiring additional labelling phrase
The substances referred to in regulation 9(3A) are specified in the table below
Carcinogenic substance of Category 1
| Substances | Index Number | EC number | CAS number | Notes |
|---|---|---|---|---|
| Chromium trioxide | 024-001-00-0 | 215-607-8 | 1333-82-0 | 1333-82-0 |
| Zinc chromates including zinc potassium chromate | 024-007-00-3 | 024-007-00-3 | 024-007-00-3 | 024-007-00-3 |
| nickel monoxide | 028-003-00-2 | 215-215-7 | 1313-99-1 | 1313-99-1 |
| nickel dioxide | 028-004-00-8 | 234-823-3 | 12035-36-8 | 12035-36-8 |
| dinickel trioxide | 028-005-00-3 | 215-217-8 | 1314-06-3 | 1314-06-3 |
| nickel sulphide | 028-006-00-9 | 240-841-2 | 16812-54-7 | 16812-54-7 |
| nickel subsulphide | 028-007-00-4 | 234-829-6 | 12035-72-2 | 12035-72-2 |
| diarsenic trioxide; arsenic trioxide | 033-003-00-0 | 215-481-4 | 1327-53-3 | 1327-53-3 |
| arsenic pentoxide; arsenic oxide | 033-004-00-6 | 215-116-9 | 1303-28-2 | 1303-28-2 |
| arsenic acid and its salts | 033-005-00-1 | 033-005-00-1 | 033-005-00-1 | 033-005-00-1 |
| lead hydrogen arsenate | 082-011-00-0 | 232-064-2 | 7784-40-9 | 7784-40-9 |
| benzene | 601-020-00-8 | 200-753-7 | 71-43-2 | 71-43-2 |
| vinyl chloride; chloroethylene | 602-023-00-7 | 200-831-0 | 75-01-4 | 75-01-4 |
| Bis (chloromethyl) ether | 603-046-00-5 | 208-832-8 | 542-88-1 | 542-88-1 |
| Chloromethyl methyl ether; chlorodimethyl ether | 603-075-00-3 | 203-408-1 | 107-30-2 | 107-30-2 |
| 2-naphthylamine; beta-naphthylamine | 612-022-00-3 | 202-080-4 | 91-59-8 | 91-59-8 |
| benzidine; 4,4’-diaminobiphenyl; biphenyl-4,4’-ylenediamine | 612-042-00-2 | 202-199-1 | 92-87-5 | 92-87-5 |
| salts of benzidine | 612-070-00-5 | 612-070-00-5 | 612-070-00-5 | 612-070-00-5 |
| salts of 2-naphthylamine | 612-071-00-0 | 612-071-00-0 | 612-071-00-0 | 612-071-00-0 |
| biphenyl-4-ylamine; xenylamine; 4-aminobiphenyl | 612-072-00-6 | 202-177-1 | 92-67-1 | 92-67-1 |
| salts of biphenyl-4-ylamine; salts of xenylamine; salts of 4-aminobiphenyl | 612-073-00-1 | 612-073-00-1 | 612-073-00-1 | 612-073-00-1 |
| Tar, coal; coal tar (The by-product from the destructive distillation of coal. Almost black semisolid. A complex combination of aromatic hydrocarbons, phenolic compounds, nitrogen bases and thiophene.) | 648-081-00-7 | 232-361-7 | 8007-45-2 | 8007-45-2 |
| Tar, coal, high-temp.; Coal tar (The condensation product obtained by cooling, to approximately ambient temperature, the gas evolved in the high temperature (greater than 700°C (1292°F)) destructive distillation of coal. A black viscous liquid denser than water. Composed primarily of a complex mixture of condensed ring aromatic hydrocarbons. May contain minor amounts of phenolic compounds and aromatic nitrogen bases.) | 648-082-00-2 | 266-024-0 | 65996-89-6 | 65996-89-6 |
| Tar, coal, low-temp.; Coal oil (The condensation product obtained by cooling, to approximately ambient temperature, the gas evolved in low temperature (less than 700°C (1292°F)) destructive distillation of coal. A black viscous liquid denser than water. Composed primarily of condensed ring aromatic hydrocarbons, phenolic compounds, aromatic nitrogen bases, and their alkyl derivatives.) | 648-083-00-8 | 266-025-6 | 65996-90-9 | 65996-90-9 |
| Tar brown-coal; (An oil distilled from brown-coal tar. Composed primarily of aliphatic, naphthenic and one-to three-ring aromatic hydrocarbons, their alkyl derivatives, heteroaromatics and one-and two-ring phenols boiling in the range of approximately 150°C to 360°C (302°F to 680°F).) | 648-145-00-4 | 309-885-0 | 101316-83-0 | 101316-83-0 |
| Tar, brown-coal, low temp; (A tar obtained from low temperature carbonization and low temperature gasification of brown coal. Composed primarily of aliphatic, naphthenic and cyclic aromatic hydrocarbons, heteroaromatic hydrocarbons and cyclic phenols.) | 648-146-00-X | 309-886-6 | 101316-84-1 | 101316-84-1 |
| Coke (coal tar), high temperature pitch | 648-157-00-X | 140203-12-9 | 140203-12-9 | |
| Coke (coal tar), mixed coal-high temperature pitch | 648-158-00-5 | 140203-13-0 | 140203-13-0 | |
| Coke (coal tar) low temperature, high temperature pitch | 648-159-00-0 | 140413-61-2 | 140413-61-2 | |
| Distillates (petroleum), light paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀ and produces a finished oil with a viscosity of less than 100 SUS at 100°F (19 cS at 40°C). It contains a relatively large proportion of saturated aliphatic hydrocarbons normally present in this distillation range of crude oil.) | 649-050-00-0 | 265-051-5 | 64741-50-0 | 64741-50-0 |
| Distillates (petroleum), heavy paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains a relatively large proportion of saturated aliphatic hydrocarbons.) | 649-051-00-6 | 265-052-0 | 64741-51-1 | 64741-51-1 |
| Distillates (petroleum), light naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-052-00-1 | 265-053-6 | 64741-52-2 | 64741-52-2 |
| Distillates (petroleum), heavy naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by vacuum distillation of the residuum from atmospheric distillation of crude oil. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-053-00-7 | 265-054-1 | 64741-53-3 | 64741-53-3 |
| Distillates (petroleum), acid-treated heavy naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid treating process. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-054-00-2 | 265-117-3 | 64742-18-3 | 64742-18-3 |
| Distillates (petroleum), acid-treated light naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid treating process. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-055-00-8 | 265-118-9 | 64742-19-4 | 64742-19-4 |
| Distillates (petroleum), acid-treated heavy paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid process. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C).) | 649-056-00-3 | 265-119-4 | 64742-20-7 | 64742-20-7 |
| Distillates (petroleum), acid-treated light paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained as a raffinate from a sulfuric acid treating process. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C).) | 649-057-00-9 | 265-121-5 | 64742-21-8 | 64742-21-8 |
| Distillates (petroleum), chemically neutralized heavy paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons obtained from a treating process to remove acidic materials. It consists predominantly of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains a relatively large proportion of aliphatic hydrocarbons.) | 649-058-00-4 | 265-127-8 | 64742-27-4 | 64742-27-4 |
| Distillates (petroleum), chemically neutralized light paraffinic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by a treating process to remove acidic materials. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with viscosity of at least 100 SUS at 100°F (19 cSt at 40°C).) | 649-059-00-X | 265-128-3 | 64742-28-5 | 64742-28-5 |
| Distillates (petroleum), chemically neutralized heavy naphthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by a treating process to remove acidic materials. It consists of hydrocarbons having carbon numbers predominantly in the range of C₂₀ through C₅₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-060-00-5 | 265-135-1 | 64742-34-3 | 64742-34-3 |
| Distillates (petroleum), chemically neutralized light napthenic; Unrefined or mildly refined baseoil (A complex combination of hydrocarbons produced by a treating process to remove acidic materials. It consists of hydrocarbons having carbon numbers predominantly in the range of C₁₅ through C₃₀, and produces a finished oil with a viscosity of at least 100 SUS at 100°F (19 cSt at 40°C). It contains relatively few normal paraffins.) | 649-061-00-0 | 265-136-7 | 64742-35-4 | 64742-35-4 |
| erionite | 650-012-00-0 | 12510-42-8 | 12510-42-8 | |
| asbestos | 650-013-00-6 | 132207-33-1 132207-32-0 12172-73-5 77536-66-4 77536-68-6 77536-67-5 | 132207-33-1 132207-32-0 12172-73-5 77536-66-4 77536-68-6 77536-67-5 |
Carcinogenic substances of Category 2
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