The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002

Made: 28th June 2002

Laid before Parliament: 3rd July 2002

Coming into force: 24th July 2002

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PART I — PRELIMINARY

Citation, commencement and extent

1

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Interpretation

2

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Application

3

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PART II — GENERAL REQUIREMENTS

Classification of dangerous substances and dangerous preparations

4

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Safety data sheets for dangerous substances, dangerous preparations and certain other preparations

5

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Advertisements for dangerous substances and dangerous preparations

6

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Packaging of dangerous substances and dangerous preparations

7

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Labelling of dangerous substances and dangerous preparations

8

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Particular labelling requirements for certain preparations

9

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Methods of marking or labelling packages

10

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Child resistant fastenings, tactile warning devices and other consumer protection measures

11

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Retention of data for dangerous preparations

12

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PART III — MISCELLANEOUS

Exemption certificates

13

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Enforcement

14

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Defence

15

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Transitional provisions

16

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Extension outside Great Britain

17

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Revocations and modifications

18

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SCHEDULE 1 — CLASSIFICATION OF DANGEROUS SUBSTANCES AND DANGEROUS PREPARATIONS

CATEGORIES OF DANGER

Column 1	Column 2	Column 3
Category of danger	Property (See Note 1)	Symbol-letter
NotesAs further described in the approved classification and labelling guide.The categories are specified in the approved classification and labelling guide.In certain cases specified in the approved supply list and in the approved classification and labelling guide substances and preparations classified as dangerous for the environment do not require to be labelled with the symbol and indication of danger.	NotesAs further described in the approved classification and labelling guide.The categories are specified in the approved classification and labelling guide.In certain cases specified in the approved supply list and in the approved classification and labelling guide substances and preparations classified as dangerous for the environment do not require to be labelled with the symbol and indication of danger.	NotesAs further described in the approved classification and labelling guide.The categories are specified in the approved classification and labelling guide.In certain cases specified in the approved supply list and in the approved classification and labelling guide substances and preparations classified as dangerous for the environment do not require to be labelled with the symbol and indication of danger.
PHYSICO-CHEMICAL PROPERTIES	PHYSICO-CHEMICAL PROPERTIES
Explosive	Solid, liquid, pasty or gelatinous substances and preparations which may react exothermically without atmospheric oxygen thereby quickly evolving gases, and which under defined test conditions detonate, quickly deflagrate or upon heating explode when partially confined.	E
Oxidising	Substances and preparations which give rise to a highly exothermic reaction in contact with other substances, particularly flammable substances.	O
Extremely flammable	Liquid substances and preparations having an extremely low flash point and a low boiling point and gaseous substances and preparations which are flammable in contact with air at ambient temperature and pressure.	F+
Highly flammable	The following substances and preparations, namely—	F
	asubstances and preparations which may become hot and finally catch fire in contact with air at ambient temperature without any application of energy,
	bsolid substances and preparations which may readily catch fire after brief contact with a source of ignition and which continue to burn or to be consumed after removal of the source of ignition,
	cliquid substances and preparations having a very low flash point, or
	dsubstances and preparations which, in contact with water or damp air, evolve extremely flammable gases in dangerous quantities.
Flammable	Liquid substances and preparations having a low flash point.	none
HEALTH EFFECTS	HEALTH EFFECTS
Very toxic	Substances and preparations which in very low quantities cause death or acute or chronic damage to health when inhaled, swallowed or absorbed via the skin.	T+
Toxic	Substances and preparations which in low quantities cause death or acute or chronic damage to health when inhaled, swallowed or absorbed via the skin.	T
Harmful	Substances and preparations which may cause death or acute or chronic damage to health when inhaled, swallowed or absorbed via the skin.	Xn
Corrosive	Substances and preparations which may, on contact with living tissues, destroy them.	C
Irritant	Non-corrosive substances and preparations which, through immediate, prolonged or repeated contact with the skin or mucous membrane, may cause inflammation.	Xi
Sensitising	Substances and preparations which, if they are inhaled or if they penetrate the skin, are capable of eliciting a reaction by hypersensitization such that on further exposure to the substance or preparation, characteristic adverse effects are produced.
Sensitising by inhalation		Xn
Sensitising by skin contact		Xi
Carcinogenic (See Note 2)	Substances and preparations which, if they are inhaled or ingested or if they penetrate the skin, may induce cancer or increase its incidence
Category 1		T
Category 2		T
Category 3		Xn
Mutagenic (See Note 2)	Substances and preparations which, if they are inhaled or ingested or if they penetrate the skin, may induce heritable genetic defects or increase their incidence.
Category 1		T
Category 2		T
Category 3		Xn
Toxic for reproduction (See Note 2)	Substances and preparations which, if they are inhaled or ingested or if they penetrate the skin, may produce or increase the incidence of non-heritable adverse effects in the progeny and/or of male or female reproductive functions or capacity.
Category 1		T
Category 2		T
Category 3		Xn
ENVIRONMENTAL EFFECTS	ENVIRONMENTAL EFFECTS
Dangerous for the environment (See Note 3)	Substances and preparations which, were they to enter into the environment, would present or might present an immediate or delayed danger for one or more components of the environment.	N

SCHEDULE 2 — INDICATIONS OF DANGER AND SYMBOLS FOR DANGEROUS SUBSTANCES AND DANGEROUS PREPARATIONS

Column 1	Column 2	Column 3
Indication of danger	Symbol-letter	Symbol
Explosive	E	[image omitted]
Oxidising	O	[image omitted]
Extremely flammable	F+	[image omitted]
Highly flammable	F	[image omitted]
Very toxic	T+	[image omitted]
Toxic	T	[image omitted]
Harmful	Xn	[image omitted]
Corrosive	C	[image omitted]
Irritant	Xi	[image omitted]
Dangerous for the environment	N	[image omitted]

SCHEDULE 3 — PROVISIONS FOR CLASSIFYING DANGEROUS PREPARATIONS

PART I — GENERAL PROVISIONS

Application

1

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Interpretation and application

2

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Classification of preparations by physico-chemical properties

3

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Classification of preparations by health effects

4

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Classification for health effects by the conventional method

5

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Lower limits of concentration

6

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Classification by the conventional method as very toxic

7

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Classification by the conventional method as toxic

8

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Classification by the conventional method as harmful

9

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Classification by the conventional method as corrosive

10

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Classification by the conventional method as irritant

11

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Classification by the conventional method as sensitising

12

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Classification by the conventional method as carcinogenic

13

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Classification by the conventional method as mutagenic

14

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Classification by the conventional method as toxic for reproduction

15

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Classification of preparations by environmental hazards

16

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Classification for environmental hazards by the conventional method

17

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Conventional method for the evaluation of hazards to the aquatic environment

18

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Conventional method for the evaluation of hazards to the ozone layer

19

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PART II — CONCENTRATION LIMITS TO BE USED IN APPLYING THE CONVENTIONAL METHOD OF ASSESSING HEALTH EFFECTS IN ACCORDANCE WITH PART I OF THIS SCHEDULE WHERE NO SUCH LIMITS ARE GIVEN IN THE APPROVED SUPPLY LIST

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For that purpose the dangerous health effects have been subdivided into:

• (1) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

• (2) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

• (3) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

• (4) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

• (5) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

• (6) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

The systematic assessment of the dangerous health effects is expressed by means of concentration limits, expressed as weight/weight percentage except for gaseous preparations (Tables A) where they are expressed as a volume/volume percentage and in conjunction with the classification of a substance.

The classification of the substance is expressed either by a symbol and one or more risk phrases or by categories (category 1, category 2 or category 3) also expressed by risk phrases when substances are shown to be carcinogenic, mutagenic or toxic for reproduction. Therefore it is important to consider, in addition to the symbol, all the phrases denoting specific risks which are assigned to each substance under consideration.

Acute lethal effects

1

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1.1

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Gaseous preparations

1.2

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Non-lethal irreversible effects after a single exposure

2

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Other than gaseous preparations

2.1

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Gaseous preparations

2.2

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Severe effects after repeated or prolonged exposure

3

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Other than gaseous preparations

3.1

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Gaseous preparations

3.2

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Corrosive and irritant effects including serious damage to eye

4

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Other than gaseous preparations

4.1

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Note

Simple application of the conventional method to preparations containing substances classified as corrosive or irritant may result in under-classification or over-classification of the hazard, if other relevant factors (e.g. pH of the preparation) are not taken into account. Therefore, in classifying for corrosivity, consider the advice given in the approved classification and labelling guide regarding classification as corrosive and paragraph 4(4)(b) and (c) of Part I of this Schedule.

Gaseous preparations

4.2

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Note

Simple application of the conventional method to preparations containing substances classified as corrosive or irritant may result in under-classification or over-classification of the hazard, if other relevant factors (e.g. pH of the preparation) are not taken into account. Therefore, in classifying for corrosivity, consider the advice given in the approved classification and labelling guide regarding classification as corrosive and paragraph 4(4)(b) and (c) of Part I of this Schedule.

Sensitising effects

5

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Other than gaseous preparations

5.1

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Gaseous preparations

5.2

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Carcinogenic/mutagenic/toxic effects for reproduction

6

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Other than gaseous preparations

6.1

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Gaseous preparations

6.2

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PART III — CONCENTRATION LIMITS TO BE USED FOR THE EVALUATION OF ENVIRONMENT HAZARDS

The aquatic environment

1

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The non-aquatic environment

2

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SCHEDULE 4 — HEADINGS UNDER WHICH PARTICULARS ARE TO BE PROVIDED IN SAFETY DATA SHEETS

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1

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2

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3

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4

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5

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6

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7

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8

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9

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10

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11

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12

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13

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14

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15

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16

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SCHEDULE 5 — LABELLING PARTICULARS FOR DANGEROUS SUBSTANCES, DANGEROUS PREPARATIONS AND FOR CERTAIN OTHER PREPARATIONS

PART I — GENERAL PROVISIONS RELATING TO LABELS

Labelling particulars for dangerous substances

1

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Labelling particulars for dangerous preparations

2

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Confidentiality of chemical names

3

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Indications of danger and symbols for dangerous substances and dangerous preparations

4

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PART II — PARTICULAR PROVISIONS CONCERNING CERTAIN PREPARATIONS

A — SPECIAL PROVISIONS FOR DANGEROUS PREPARATIONS

Dangerous preparations to be supplied to the general public

1

• (1) The labels on packages of dangerous preparations intended to be supplied to the general public must bear relevant safety phrase S1, S2, S45 or S46 in accordance with the approved classification and labelling guide.

• (2) When the dangerous preparations referred to in sub-paragraph (1) are classified as very toxic, toxic or corrosive and where it is physically impossible to give the information on the package itself, packages containing such preparations must be accompanied by precise and easily understandable instructions for use including, where appropriate, instructions for the destruction of the empty package.

Dangerous preparations intended for use by spraying

2

The labels on packages containing dangerous preparations intended to be used for spraying shall bear the safety phrase S23 and safety phrase S38 or S51 assigned in accordance with the approved classification and labelling guide.

Dangerous preparations containing a substance affected by the risk phrase R33 (danger of cumulative effects)

3

When a dangerous preparation contains at least one substance required to show the risk phrase R33, that phrase must be shown on the label of the dangerous preparation when the concentration of that substance is equal to or higher than 1% unless a different value is shown for that substance in the approved supply list.

Dangerous preparations containing a substance affected by the risk phrase R64 (may cause harm to breast-fed babies)

4

When a dangerous preparation contains at least one substance required to show the risk phrase R64, that phrase must be shown on the label of the dangerous preparation when the concentration of that substance is equal to or higher than 1% unless a different value is shown for that substance in the approved supply list.

B — SPECIAL PROVISIONS APPLYING TO ANY PREPARATION

Paints and varnishes containing lead

1

• (1) Labels of packages of paints and varnishes containing lead in quantities exceeding 0.15% (expressed as weight of lead out of the total weight of the preparation and determined in accordance with ISO Standard 6503/1984) shall bear the following inscription—

• Contains lead. Should not be used on surfaces that are liable to be chewed or sucked by children.

• (2) In the case of packages containing less than 125 millilitres of the preparations referred to in sub-paragraph (1), the inscription on the label may be—

• Warning. Contains lead.

Cyanoacrylate based adhesives

2

• (1) The immediate packages of glues based on cyanoacrylates shall bear the following inscription—

• Cyanoacrylate.
• Danger.
• Bonds skin and eyes in seconds.
• Keep out of the reach of children.

• (2) Appropriate safety advice shall accompany the package.

Preparations containing isocyanates

3

The package labels of preparations containing isocyanates (whether as monomers, oligomers, prepolymers etc. or as mixtures thereof) shall bear the following inscriptions—

• Contains isocyanates.
• See information supplied by the manufacturer.

Certain preparations containing epoxy constituents

4

The package labels of preparations containing epoxy constituents with an average molecular weight ≤700 shall bear the following inscription—

• Contains epoxy constituents.
• See information supplied by the manufacturer.

Preparations intended to be sold to the general public that contain active chlorine

5

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Preparations containing cadmium (alloys) intended to be used for brazing or soldering

6

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Preparations containing substances not yet tested completely

7

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Preparations not classified as sensitising but containing at least one sensitising substance

8

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Liquid preparations containing halogenated hydrocarbons

9

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Preparations containing a substance assigned the risk phrase R67

10

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Cement and cement preparations

11

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

C — SPECIAL PROVISIONS APPLYING TO CERTAIN OTHER PREPARATIONS

Preparations not intended for the general public

1

The label on the packaging of a preparation of the type specified in regulation 5(3) must bear the following inscription—

• Safety data sheet available for professional user on request.

SCHEDULE 6 — BRITISH AND INTERNATIONAL STANDARDS RELATING TO CHILD RESISTANT FASTENINGS AND TACTILE WARNING DEVICES

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SCHEDULE 7 — REVOCATIONS

1	2	3
Regulations revoked	References	Extent of revocation
The Chemicals (Hazard Information and Packaging for Supply) Regulations 1994	S.I. 1994/3247	The whole Regulations
The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 1996	S.I. 1996/1092	The whole Regulations
The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 1997	S.I. 1997/1460	The whole Regulations
The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 1998	S.I. 1998/3106	The whole Regulations
The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 1999	S.I. 1999/197	The whole Regulations
The Chemicals (Hazard Information and Packaging for Supply) (Amendment) (No. 2) Regulations 1999	S.I. 1999/3165	The whole Regulations
The Chemicals (Hazard Information and Packaging for Supply) (Amendment) Regulations 2000	S.I. 2000/2381	The whole Regulations

Signed

David Jamieson — Parliamentary Under-Secretary of State, — Department for Transport — 28th June 2002

Explanatory note

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Footnotes

[^f00001]: S.I. 1976/897 and S.I. 1993/2661.

[^f00002]: 1972 c. 68.

[^f00003]: As regards Scotland, see also section 57(1) of the Scotland Act 1998 (c. 46), which provides that, despite the transfer to the Scottish Ministers by virtue of that Act of functions in relation to observing and implementing obligations under Community law, any function of a Minister of the Crown in relation to any matter shall continue to be exercisable by him as regards Scotland for the purposes specified in section 2(2) of the European Communities Act 1972.

[^f00004]: 1974 c. 37; sections 15(1) and 50(3) were amended by the Employment Protection Act 1975 (c. 71), Schedule 15, paragraphs 6 and 16(3) respectively.

[^f00006]: The Agreement was amended by Decision 7/94 of the EEA Joint Committee of 21st March 1994 (OJ No. L160, 28.6.94, p. 1). There are other amendments to the Agreement which are not relevant to these Regulations.

[^f00007]: 1993 c. 51.

[^f00008]: OJ No. C146A, 15.6.90, p.1.

[^f00009]: OJ No. C130, 10.5.93, p.1.

[^f00010]: S.I. 1993/3050, to which there are amendments not relevant to these Regulations.

[^f00011]: S.I. 1995/887, to which there are amendments not relevant to these Regulations.

[^f00012]: 1968 c. 67.

[^f00013]: 1971 c. 38.

[^f00014]: S.I. 1996/2925, to which there are amendments not relevant to these Regulations.

[^f00015]: S.I. 1994/1056, to which there are amendments not relevant to these Regulations.

[^f00016]: S.I. 1996/972, to which there are amendments not relevant to these Regulations.

[^f00017]: 1990 c. 16.

[^f00018]: 1970 c. 40; section 66(1) was modified by S.I. 1991/2840.

[^f00019]: S.I. 2002/618.

[^f00021]: S.I. 1986/1510, to which there are amendments not relevant to these Regulations.

[^f00022]: 1987 c. 43.

[^f00023]: S.I. 1997/2367.

[^f00024]: S.I. 1994/3187.

[^f00026]: S.I. 1999/3107.

[^f00027]: 1928 c. 32.

[^f00028]: S.I. 1972/917, to which there are amendments not relevant to these Regulations.

[^f00029]: S.I. 1971/729.

[^f00030]: S.I. 1986/1510, to which there are amendments not relevant to these Regulations.

[^f00031]: S.I. 1998/494.

[^f00032]: 1968 c. 67; section 75(8) was amended by S.I. 1968/1699.

[^f00033]: 1987 c. 43; section 11(7)(c) is amended by section 16(1) of, and paragraph 15 of Schedule 4 to, the Gas Act 1995.

[^f00034]: S.I. 1994/3247, as amended by S.I.s 1996/1092, 1997/1460, 1998/3106, 1999/197, 1999/3165, 1999/3194, 2000/2381 and 2000/2897.

[^f00035]: S.I. 2001/880.

[^f00036]: S.I. 1986/1510, to which there are amendments not relevant to these Regulations.

[^f00037]: O.J. No. L123, 24.4.98, p. 1.

[^f00038]: S.I. 2001/2127.

[^f00039]: OJ No. L147, 9.6.1975, p.40.

[^f00040]: OJ No. L200, 30.7.1999, p.1.

Editorial notes

Labelling of single receptacles and receptacles in outer packagings

8A

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Particular labelling requirements for certain preparations

Methods of marking or labelling packages

Child resistant fastenings, tactile warning devices and other consumer protection measures

Retention of data for dangerous preparations

1

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12

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