The Water Supply (Water Quality) Regulations 2001

Type Welsh-Statutory-Instrument
Publication 2001-12-07
Last updated 2010-04-20
State In force
Jurisdiction Wales
Department King's Printer of Acts of Parliament
PDF Download
articles Not indexed
Reform history JSON API

Made: 7th December 2001

Laid before Parliament: 10th December 2001

Coming into force in accordance with regulation 1(2) to (5)

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PART I — GENERAL

Citation, commencement and application

1

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Interpretation

2

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PART II — WATER SUPPLY ZONES

Water supply zones

3

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PART III — WHOLESOMENESS

Wholesomeness

4

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PART IV — MONITORING OF WATER SUPPLIES

Interpretation and application of Part IV

5

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Monitoring: general provisions

6

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Sampling points

7

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Authorisation of supply points

8

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Numbers of samples

9

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Sampling: further provisions

10

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PART V — MONITORING — ADDITIONAL PROVISIONS

Interpretation of Part V

11

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Sampling for particular substances and parameters

12

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Sampling at treatment works

13

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Sampling at service reservoirs

14

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Sampling: new sources

15

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Collection and analysis of samples

16

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PART VI — INVESTIGATIONS, AUTHORISATION OF DEPARTURES AND REMEDIAL ACTION

Investigations: Schedule 1 parameters

17

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Investigations: indicator parameters

18

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Action by National Assembly for Wales

19

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Authorisation of temporary supply of water that is not wholesome

20

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Authorisations: terms and conditions

21

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Authorisations: other limitations

22

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Publicity for authorisations

23

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Revocation and modification of authorisations

24

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PART VII — WATER TREATMENT

Interpretation

25

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Treatment of raw water

26

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Risk assessment for cryptosporidium

27

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Procedure following risk assessment and prohibition of supply

28

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Treatment for cryptosporidium

29

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Contamination from pipes

30

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Application and introduction of substances and products

31

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Use of processes

32

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Offences

33

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PART VIII — RECORDS AND INFORMATION

Maintenance of records

34

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Provision of information

35

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Publication of information

36

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PART IX — FUNCTIONS OF LOCAL AUTHORITIES IN RELATION TO WATER QUALITY

Application and interpretation

37

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Duties of local authorities: supplementary provision

38

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PART X — ENFORCEMENT

Contraventions by water undertakers

39

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PART XI — AMENDMENT AND REVOCATION OF REGULATIONS AND SAVING AND TRANSITIONAL PROVISION

Amendment of the Water Supply (Water Quality) Regulations 1989

40

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Transitional provision: programmes of work

41

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Transitional provision: authorisations

42

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Revocation of Regulations and savings

43

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SCHEDULE 1 — PRESCRIBED CONCENTRATIONS AND VALUES

TABLE A — MICROBIOLOGICAL PARAMETERS

Item Parameters Concentration or Value (maximum) Units of Measurement Point of compliance
1. Enterococci 0 number/100ml Consumers' taps
2. Escherichia coli (E. coli) 0 number/100ml Consumers' taps
Item Parameters Concentration or Value (maximum) Units of Measurement Point of compliance
--- --- --- --- ---
Note: Note: Note: Note: Note:
* Compliance required as to 95% of samples from each service reservoir (regulation 4(6)). * Compliance required as to 95% of samples from each service reservoir (regulation 4(6)). * Compliance required as to 95% of samples from each service reservoir (regulation 4(6)). * Compliance required as to 95% of samples from each service reservoir (regulation 4(6)). * Compliance required as to 95% of samples from each service reservoir (regulation 4(6)).
1. Coliform bacteria 0 number/100ml Service reservoirs[^f01000] and water treatment works
2. Escherichia coli (E. coli) 0 number/100ml Service reservoirs and water treatment works

TABLE B — CHEMICAL PARAMETERS

Item Parameters Concentration or Value (maximum) Units of Measurement Point of compliance
Notes: Notes: Notes: Notes: Notes:
(i) The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. This is controlled by product specification. (i) The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. This is controlled by product specification. (i) The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. This is controlled by product specification. (i) The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. This is controlled by product specification. (i) The parametric value refers to the residual monomer concentration in the water as calculated according to specifications of the maximum release from the corresponding polymer in contact with the water. This is controlled by product specification.
(ii) See also regulation 6(6). (ii) See also regulation 6(6). (ii) See also regulation 6(6). (ii) See also regulation 6(6). (ii) See also regulation 6(6).
(iii) See also regulation 4(2)(d). (iii) See also regulation 4(2)(d). (iii) See also regulation 4(2)(d). (iii) See also regulation 4(2)(d). (iii) See also regulation 4(2)(d).
(iv) See the definition of “pesticides and related products” in regulation 2. (iv) See the definition of “pesticides and related products” in regulation 2. (iv) See the definition of “pesticides and related products” in regulation 2. (iv) See the definition of “pesticides and related products” in regulation 2. (iv) See the definition of “pesticides and related products” in regulation 2.
(v) The parametric value applies to each individual pesticide. (v) The parametric value applies to each individual pesticide. (v) The parametric value applies to each individual pesticide. (v) The parametric value applies to each individual pesticide. (v) The parametric value applies to each individual pesticide.
(vi) “Pesticides: Total” means the sum of the concentrations of the individual pesticides detected and quantified in the monitoring procedure. (vi) “Pesticides: Total” means the sum of the concentrations of the individual pesticides detected and quantified in the monitoring procedure. (vi) “Pesticides: Total” means the sum of the concentrations of the individual pesticides detected and quantified in the monitoring procedure. (vi) “Pesticides: Total” means the sum of the concentrations of the individual pesticides detected and quantified in the monitoring procedure. (vi) “Pesticides: Total” means the sum of the concentrations of the individual pesticides detected and quantified in the monitoring procedure.
(vii) The specified compounds are: benzo(b)fluoranthene benzo(k)fluoranthene benzo(ghi)perylene indeno(1,2,3-cd)pyrene. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (vii) The specified compounds are: benzo(b)fluoranthene benzo(k)fluoranthene benzo(ghi)perylene indeno(1,2,3-cd)pyrene. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (vii) The specified compounds are: benzo(b)fluoranthene benzo(k)fluoranthene benzo(ghi)perylene indeno(1,2,3-cd)pyrene. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (vii) The specified compounds are: benzo(b)fluoranthene benzo(k)fluoranthene benzo(ghi)perylene indeno(1,2,3-cd)pyrene. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (vii) The specified compounds are: benzo(b)fluoranthene benzo(k)fluoranthene benzo(ghi)perylene indeno(1,2,3-cd)pyrene. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process.
(viii) The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (viii) The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (viii) The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (viii) The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (viii) The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process.
(ix) The specified compounds are: chloroform bromoform dibromochloromethane bromodichloromethane. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (ix) The specified compounds are: chloroform bromoform dibromochloromethane bromodichloromethane. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (ix) The specified compounds are: chloroform bromoform dibromochloromethane bromodichloromethane. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (ix) The specified compounds are: chloroform bromoform dibromochloromethane bromodichloromethane. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process. (ix) The specified compounds are: chloroform bromoform dibromochloromethane bromodichloromethane. The parametric value applies to the sum of the concentrations of the individual compounds detected and quantified in the monitoring process.
1. Acrylamide 0.10 μg/l [^f01001]
2. Antimony 5.0 μgSb/l Consumers' taps
3. Arsenic 10 μgAs/l Consumers' taps
4. Benzene 1.0 μg/l Consumers' taps
5. Benzo(a)pyrene 0.010 μg/l Consumers' taps
6. Boron 1.0 mgB/l Consumers' taps
7. Bromate 10 μgBrO₃/l Consumers' taps
8. Cadmium 5.0 μgCd/l Consumers' taps
9. Chromium 50 μgCr/l Consumers' taps
10. Copper[^f01002] 2.0 mgCu/l Consumers' taps
11. Cyanide 50 μgCN/l Consumers' taps
12. 1, 2 dichloroethane 3.0 μg/l Consumers' taps
13. Epichlorohydrin 0.10 μg/l [^f01001]
14. Fluoride 1.5 mgF/l Consumers' taps
15. Lead[^f01002] a 25, from 25th December 2003 until immediately before 25th December 2013 μgPb/l Consumers' taps
b 10, on and after 25th December 2013 μgPb/l Consumers' taps
16. Mercury 1.0 μgHg/l Consumers' taps
17. Nickel [^f01002] 20 μgNi/l Consumers' taps
18. Nitrate [^f01003] 50 mgNO₃/l Consumers' taps
19. Nitrite [^f01003] 0.50 mgNO₂/l Consumers' taps
0.10 Treatment Works
20. Pesticides [^f01004][^f01005] Aldrin ) Dieldrin ) Heptachlor ) Heptachlor ) epoxide ) 0.030 μg/l Consumers' taps
other pesticides 0.10 μg/l Consumers' taps
21. Pesticides: Total [^f01006] 0.50 μg/l Consumers' taps
22. Polycyclic aromatic hydrocarbons [^f01007] 0.10 μg/l Consumers' taps
23. Selenium 10 μgSe/l Consumers' taps
24. Tetrachloroethene and Trichloroethene [^f01008] 10 μg/l Consumers' taps
25. Trihalomethanes: Total [^f01009] 100 μg/l Consumers' taps
26. Vinyl chloride 0.50 μg/l [^f01001]
Item Parameters Concentration or Value (maximum unless otherwise stated) Units of Measurement Point of compliance
--- --- --- --- ---
1. Aluminium 200 μgAl/l Consumers' taps
2. Colour 20 mg/l Pt/Co Consumers' taps
3. Hydrogen ion 10.0 pH value Consumers' taps
6.5 (minimum) pH value Consumers' taps
4. Iron 200 μgFe/l Consumers' taps
5. Manganese 50 μgMn/l Consumers' taps
6. Odour 3 at 25°C Dilution number Consumers' taps
7. Sodium 200 mgNa/l Consumers' taps
8. Taste 3 at 25°C Dilution number Consumers' taps
9. Tetrachlorome-thane 3 μg/l Consumers' taps
10. Turbidity 4 NTU Consumers' taps

SCHEDULE 2 — INDICATOR PARAMETERS

Item Parameters Specification Concentration or Value (maximum) or State Units of Measurement Point of monitoring
Notes: Notes: Notes: Notes: Notes:
(i) The water should not be aggressive. (i) The water should not be aggressive. (i) The water should not be aggressive. (i) The water should not be aggressive. (i) The water should not be aggressive.
(ii) Excluding tritium, potassium-40, radon and radon decay products. (ii) Excluding tritium, potassium-40, radon and radon decay products. (ii) Excluding tritium, potassium-40, radon and radon decay products. (ii) Excluding tritium, potassium-40, radon and radon decay products. (ii) Excluding tritium, potassium-40, radon and radon decay products.
* May be monitored from samples of water leaving treatment works or other supply point, as no significant change during distribution. * May be monitored from samples of water leaving treatment works or other supply point, as no significant change during distribution. * May be monitored from samples of water leaving treatment works or other supply point, as no significant change during distribution. * May be monitored from samples of water leaving treatment works or other supply point, as no significant change during distribution. * May be monitored from samples of water leaving treatment works or other supply point, as no significant change during distribution.
1. Ammonium 0.50 mgNH₄/l Consumers' taps
2. Chloride [^f01010] 250 mgCl/l Supply point[^f01012]
3. Clostridium perfringens (including spores) 0 Number/100ml Supply point[^f01012]
4. Coliform bacteria 0 Number/100ml Consumers' taps
5. Colony counts No abnormal change Number/1ml at 22°C Consumers' taps, service
Number/1ml at 37°C Reservoirs and treatment works
6. Conductivity [^f01010] 2500 μS/cm at 20°C Supply point[^f01012]
7. Hydrogen ion 9.5 pHvalue Consumers' taps
8. Sulphate [^f01010] 250 mgSO₄ /l Supply point[^f01012]
9. Total indicative dose (for radioactivity) [^f01011] 0.10 mSv/year Supply point[^f01012]
10. Total organic carbon (TOC) No abnormal change mgC/l Supply point[^f01012]
11. Tritium (for radioactivity) 100 Bq/l Supply point[^f01012]
12. Turbidity 1 NTU Treatment works

SCHEDULE 3 — MONITORING

TABLE 1 — PARAMETERS AND CIRCUMSTANCES FOR CHECK MONITORING

(1) (2) (3)
Item Parameter Circumstances
1. Aluminium When used as flocculant or where the water originates from, or is influenced by, surface waters
2. Ammonium
3. Clostridium perfringens (including spores) Where the water originates from, or is influenced by, surface waters
4. Coliform bacteria
5. Colony counts
6. Colour
7. Conductivity
8. Escherichia coli (E. coli)
9. Hydrogen ion
10. Iron When used as flocculant or where the water originates from, or is influenced by, surface waters
11. Manganese Where the water originates from, or is influenced by, surface waters
12. Nitrate When chloramination is practised
13. Nitrite When chloramination is practised
14. Odour
15. Taste
16. Turbidity

TABLE 2 — ANNUAL SAMPLING FREQUENCIES: WATER SUPPLY ZONES

(1) (2) (3) (4)
Substances and parameters subject to check monitoring Estimated population of water supply zone Reduced Standard
Notes: Notes: Notes: Notes:
* Sampling for these parameters may be within water supply zones or at supply points as specified in Table 3, subject to notes (ii) and (iii) below. * Sampling for these parameters may be within water supply zones or at supply points as specified in Table 3, subject to notes (ii) and (iii) below. * Sampling for these parameters may be within water supply zones or at supply points as specified in Table 3, subject to notes (ii) and (iii) below. * Sampling for these parameters may be within water supply zones or at supply points as specified in Table 3, subject to notes (ii) and (iii) below.
(i) Where the population is not an exact multiple of 5,000, the population figure should be rounded up to the nearest multiple of 5,000. (i) Where the population is not an exact multiple of 5,000, the population figure should be rounded up to the nearest multiple of 5,000. (i) Where the population is not an exact multiple of 5,000, the population figure should be rounded up to the nearest multiple of 5,000. (i) Where the population is not an exact multiple of 5,000, the population figure should be rounded up to the nearest multiple of 5,000.
(ii) Check monitoring in water supply zones is required only where chloramination is practised. In other circumstances audit monitoring is required. (ii) Check monitoring in water supply zones is required only where chloramination is practised. In other circumstances audit monitoring is required. (ii) Check monitoring in water supply zones is required only where chloramination is practised. In other circumstances audit monitoring is required. (ii) Check monitoring in water supply zones is required only where chloramination is practised. In other circumstances audit monitoring is required.
(iii) Audit monitoring in water supply zones is required only where sodium hypochlorite is added after water has left the treatment works. In other circumstances, audit monitoring is required at supply points. (iii) Audit monitoring in water supply zones is required only where sodium hypochlorite is added after water has left the treatment works. In other circumstances, audit monitoring is required at supply points. (iii) Audit monitoring in water supply zones is required only where sodium hypochlorite is added after water has left the treatment works. In other circumstances, audit monitoring is required at supply points. (iii) Audit monitoring in water supply zones is required only where sodium hypochlorite is added after water has left the treatment works. In other circumstances, audit monitoring is required at supply points.
(iv) To monitor for total indicative dose (for radioactivity). (iv) To monitor for total indicative dose (for radioactivity). (iv) To monitor for total indicative dose (for radioactivity). (iv) To monitor for total indicative dose (for radioactivity).
E. coli
Coliform bacteria <100 4
Residual disinfectant ≥100 12 per 5,000 population[^f01014]
Aluminium
Ammonium
Clostridium perfringens (including spores)[^f01013] <100 1 2
100—4,999 2 4
5,000—9,999 6 12
Colony counts 10,000—29,999 12 24
Colour 30,000—49,999 18 36
Conductivity[^f01013] 50,000—79,999 26 52
Hydrogen ion 80,000—100,000 38 76
Iron
Manganese
Nitrate[^f01015]
Nitrite[^f01015]
Odour
Taste
Turbidity
Parameters subject to audit monitoring
Aluminium
Antimony
Arsenic
Benzene[^f01013] <100 1
Benzo(a)pyrene 100—4,999 4
Boron[^f01013] 5,000—100,000 8
Bromate[^f01016]
Cadmium
Chromium
Copper
Cyanide[^f01013]
1,2 dichloroethane[^f01013]
Enterococci
Fluoride[^f01013]
Iron
Lead
Manganese
Mercury[^f01013]
Nickel
Nitrate [^f01015]
Nitrite [^f01015]
Pesticides and related products[^f01013]
Polycyclic aromatic <100 1
hydrocarbons 100—4,999 4
Selenium 5,000—100,000 8
Sodium
Trichloroethene
/Tetrachloroethene[^f01013]
Tetrachloromethane[^f01013]
Trihalomethanes
Chloride[^f01013]
Sulphate[^f01013]
Total organic carbon[^f01013]
Tritium[^f01013]
Gross alpha[^f01013] [^f01017]
Gross beta[^f01013] [^f01017]

TABLE 3 — ANNUAL SAMPLING FREQUENCIES: TREATMENT WORKS OR SUPPLY POINTS*

(1) (2) (3) (4) (5)
Item Substances and parameters Volume of water supplied m³/d Reduced Standard
Notes: Notes: Notes: Notes: Notes:
* Sampling is at treatment works for the substances and parameters shown in column (1) of the Table as items 1 to 6 and at supply points for the other substances and parameters, except nitrite, subject to notes (ii) and (iii) below. * Sampling is at treatment works for the substances and parameters shown in column (1) of the Table as items 1 to 6 and at supply points for the other substances and parameters, except nitrite, subject to notes (ii) and (iii) below. * Sampling is at treatment works for the substances and parameters shown in column (1) of the Table as items 1 to 6 and at supply points for the other substances and parameters, except nitrite, subject to notes (ii) and (iii) below. * Sampling is at treatment works for the substances and parameters shown in column (1) of the Table as items 1 to 6 and at supply points for the other substances and parameters, except nitrite, subject to notes (ii) and (iii) below. * Sampling is at treatment works for the substances and parameters shown in column (1) of the Table as items 1 to 6 and at supply points for the other substances and parameters, except nitrite, subject to notes (ii) and (iii) below.
(i) Check monitoring is required only in respect of surface waters (see regulation 6(2) and Table 1 in Schedule 3). (i) Check monitoring is required only in respect of surface waters (see regulation 6(2) and Table 1 in Schedule 3). (i) Check monitoring is required only in respect of surface waters (see regulation 6(2) and Table 1 in Schedule 3). (i) Check monitoring is required only in respect of surface waters (see regulation 6(2) and Table 1 in Schedule 3). (i) Check monitoring is required only in respect of surface waters (see regulation 6(2) and Table 1 in Schedule 3).
(ii) Sampling at treatment works when chloramination is practised. (ii) Sampling at treatment works when chloramination is practised. (ii) Sampling at treatment works when chloramination is practised. (ii) Sampling at treatment works when chloramination is practised. (ii) Sampling at treatment works when chloramination is practised.
(ii) Sampling at treatment works when chloramination is not practised. (ii) Sampling at treatment works when chloramination is not practised. (ii) Sampling at treatment works when chloramination is not practised. (ii) Sampling at treatment works when chloramination is not practised. (ii) Sampling at treatment works when chloramination is not practised.
(iv) Audit monitoring at supply points is required only where sodium hypochlorite is not added after water has left the treatment works. In other circumstances, audit monitoring is required in water supply zones. (iv) Audit monitoring at supply points is required only where sodium hypochlorite is not added after water has left the treatment works. In other circumstances, audit monitoring is required in water supply zones. (iv) Audit monitoring at supply points is required only where sodium hypochlorite is not added after water has left the treatment works. In other circumstances, audit monitoring is required in water supply zones. (iv) Audit monitoring at supply points is required only where sodium hypochlorite is not added after water has left the treatment works. In other circumstances, audit monitoring is required in water supply zones. (iv) Audit monitoring at supply points is required only where sodium hypochlorite is not added after water has left the treatment works. In other circumstances, audit monitoring is required in water supply zones.
(v) To monitor for total indicative dose (for radioactivity). (v) To monitor for total indicative dose (for radioactivity). (v) To monitor for total indicative dose (for radioactivity). (v) To monitor for total indicative dose (for radioactivity). (v) To monitor for total indicative dose (for radioactivity).
1. E. Coli <20 4
2. Coliform bacteria 20—1,999 12 52
3. Colony counts 2,000—5,999 52 104
4. Nitrite [^f01020] 6,000—11,999 104 208
5. Residual disinfectant ≥12,000 104 365
6. Turbidity
Subject to check monitoring Subject to check monitoring
7. Clostridium perfringens[^f01019] <20 2
20 — 999 2 4
8. Conductivity 1,000 — 1,999 6 12
2,000 — 5,999 12 24
6,000 — 9,999 18 36
10,000 — 15,999 26 52
16,000 — 32,999 52 104
33,000 — 49,999 78 156
50,000 — 67,999 104 208
68,000 — 84,999 130 260
85,000 — 101,999 156 312
102,000 —119,999 183 365
120,000 — 241,999 365 730
242,000 — 484,999 730 1,460
485,000 — 728,999 1,095 2,190
Subject to audit monitoring Subject to audit monitoring
9. Benzene
10. Boron
11. Bromate [^f01022]
12. Cyanide
13. 1,2 dichloroethane
14. Fluoride
15. Mercury <20 1
16. Nitrite [^f01021] 20—999 4
17. Pesticides and Related products 1,000—49,999 8
50,000—89,999 12
90,000—299,999 24
300,000—649,000 36
18. Trichloroethene ) Tetrachloroethene) ≥650,000 48
19. Tetrachloromethane
20. Chloride
21. Sulphate
22. Total organic carbon
23. Tritium
24. Gross alpha [^f01023]
25. Gross beta [^f01023]

SCHEDULE 4 — ANALYTICAL METHODOLOGY

TABLE A1 — PARAMETERS FOR WHICH, SUBJECT TO REGULATION 16(7), METHODS OF ANALYSIS ARE PRESCRIBED

(1) (2)
Parameter Method
Clostridium perfringens (including spores) Membrane filtration followed by anaerobic incubation of the membrane on m-CP agar* at 44 ± 1°C for 21 ± 3 hours. Count opaque yellow colonies that turn pink or red after exposure to ammonium hydroxide vapours for 20 to 30 seconds.
Coliform bacteria ISO 9308-1
Colony count 22°C — enumeration of culturable microorganisms prEN ISO 6222
Colony count 37°C— enumeration of culturable microorganisms prEN ISO 6222
Enterococci ISO 7899-2
Escherichia coli (E. coli) ISO 9308-1

*The composition of m-CP agar is:

Basal medium
Tryptose 30.0g
Yeast extract 20.0g
Sucrose 5.0g
L-cysteine hydrochloride 1.0g
MgSO₄·7H₂O 0.1g
Bromocresol purple 40.0mg
Agar 15.0g
Water 1,000.0ml

Dissolve the ingredients of the basal medium, adjust pH to 7.6 and autoclave at 121°C for15 minutes. Allow the medium to cool and add:

D-cycloserine 400.0mg
Polymyxine-B sulphate 25.0mg
Indoxyl-[beta]-D-glucoside 60.0mg
to be dissolved in 8ml sterile water before addition
Filter — sterilised 0.5% phenolphthalein diphosphate solution 20.0ml
Filter — sterilised 4.5% FeCl₃· 6H₂O 2.0ml

TABLE A2 — PARAMETERS IN RELATION TO WHICH METHODS OF ANALYSIS MUST SATISFY PRESCRIBED CHARACTERISTICS

(1) (2) (3) (4)
Parameters Trueness % of prescribed concentration or value or specification Precision % of prescribed concentration or value or specification Limit of detection % of prescribed concentration or value or specification
Notes: Notes: Notes: Notes:
(i) The method of analysis should determine total cyanide in all forms. (i) The method of analysis should determine total cyanide in all forms. (i) The method of analysis should determine total cyanide in all forms. (i) The method of analysis should determine total cyanide in all forms.
(ii) The performance characteristics apply to each individual pesticide and will depend on the pesticide concerned. (ii) The performance characteristics apply to each individual pesticide and will depend on the pesticide concerned. (ii) The performance characteristics apply to each individual pesticide and will depend on the pesticide concerned. (ii) The performance characteristics apply to each individual pesticide and will depend on the pesticide concerned.
(iii) The performance characteristics apply to the individual substances specified at 25% of the parametric value in Part I of Table B in Schedule 1. (iii) The performance characteristics apply to the individual substances specified at 25% of the parametric value in Part I of Table B in Schedule 1. (iii) The performance characteristics apply to the individual substances specified at 25% of the parametric value in Part I of Table B in Schedule 1. (iii) The performance characteristics apply to the individual substances specified at 25% of the parametric value in Part I of Table B in Schedule 1.
(iv) The performance characteristics apply to the individual substances specified at 50% of the parametric value in Part I of Table B in Schedule 1. (iv) The performance characteristics apply to the individual substances specified at 50% of the parametric value in Part I of Table B in Schedule 1. (iv) The performance characteristics apply to the individual substances specified at 50% of the parametric value in Part I of Table B in Schedule 1. (iv) The performance characteristics apply to the individual substances specified at 50% of the parametric value in Part I of Table B in Schedule 1.
(v) The performance characteristics apply to the prescribed value of 4NTU. (v) The performance characteristics apply to the prescribed value of 4NTU. (v) The performance characteristics apply to the prescribed value of 4NTU. (v) The performance characteristics apply to the prescribed value of 4NTU.
(vi) The performance characteristics apply to the specification of 1NTU for water leaving treatment works. (vi) The performance characteristics apply to the specification of 1NTU for water leaving treatment works. (vi) The performance characteristics apply to the specification of 1NTU for water leaving treatment works. (vi) The performance characteristics apply to the specification of 1NTU for water leaving treatment works.
Aluminium 10 10 10
Ammonium 10 10 10
Antimony 25 25 25
Arsenic 10 10 10
Benzene 25 25 25
Benzo(a)pyrene 25 25 25
Boron 10 10 10
Bromate 25 25 25
Cadmium 10 10 10
Chloride 10 10 10
Chromium 10 10 10
Colour 10 10 10
Conductivity 10 10 10
Copper 10 10 10
Cyanide[^f01024] 10 10 10
1,2-dichloroethane 25 25 10
Fluoride 10 10 10
Iron 10 10 10
Lead 10 10 10
Manganese 10 10 10
Mercury 20 10 20
Nickel 10 10 10
Nitrate 10 10 10
Nitrite 10 10 10
Pesticides and related products[^f01025] 25 25 25
Polycyclic aromatic hydrocarbons[^f01026] 25 25 25
Selenium 10 10 10
Sodium 10 10 10
Sulphate 10 10 10
Tetrachloromethane 20 20 20
Trichloroethene[^f01027] 25 25 10
Trihalomethanes: Total[^f01026] 25 25 10
Turbidity[^f01028] 10 10 10
Turbidity [^f01029] 25 25 25

SCHEDULE 5 — AMENDMENT OF THE WATER SUPPLY (WATER QUALITY) REGULATIONS 1989

The amendments to the 1989 Regulations referred to in regulation 40 are—

(13A) (1) Subject to paragraphs (5) and (6), in each of the years 2002 and 2003, a water undertaker shall take, or cause to be taken, from its sampling points or, as the case may be, its supply points, for analysis for testing against the concentrations and values specified in column (2) of Table 4A for the organisms and substances listed in column (1) of that Table, not less than the number of samples specified in paragraphs (2) and (3). (2) In respect of supply points and the supply of a volume of water within a range shown in column (3) of that Table, the number is that shown in column (4) of that Table with the prefix “S” as applicable to a volume within that range. (3) In respect of sampling points and the supply of water to an estimated population within a range shown in column (5) of that Table, the number is that shown in column (6) of that Table with the prefix “S” as applicable to a population within that range. (4) In each of those years samples shall be taken at regular intervals throughout the year. (5) Where— (a) a programme of work has been approved or is treated as approved under regulation 41 (transitional provision: programmes of work) of the Water Supply (Water Quality) Regulations 2001; or has otherwise been agreed by the National Assembly for Wales; and (b) at least one of the steps required to be taken in accordance with that programme— (i) relates to an organism or substance listed in column (1) of Table 4A; and (ii) remains to be completed, the number of samples to be taken in any period of twelve months beginning with the date on which the programe was approved, treated as approved, or agreed (as the case may be) and ending on the day on which the last of those steps is completed, for analysis for testing for that organism or substance, may be the number shown in column (4) or, as the case may be, column (6) of that Table with the prefix “R”. (6) Where analysis of the samples taken by a water undertaker in 2002 in accordance with this regulation has established a concentration or value in respect of an organism or substance listed in column (1) of Table 4A that is significantly lower than the prescribed concentration or value, the number of samples to be taken in 2003, for analysis for testing for that organism or substance, may be the number shown in column (4) or, as the case may be, column (6) of that Table with the prefix “R”.

(20A) The samples taken in accordance with regulation 13 shall additionally be tested against the concentrations and values specified in column (2) of Table 4B.

(3) In relation to each of the parameters and other substances listed in column (1) of Table 4B, paragraph (2)(d) shall have effect as if for sub-paragraph (iii) there were substituted the requirements of regulation 21A.

(21A) (1) The method of analysis used for testing for a parameter or other substance listed in column (1) of Table 4B against the concentrations in column (2) of that Table must be capable, at the time of use— (a) of measuring concentrations with the trueness and precision specified in relation to that parameter or substance in columns (3) and (4) of Table 4B; and (b) of detecting the parameter or substance at the limit of detection specified in relation to it in column (5) of that Table. (2) For the purposes of paragraph (1)— - “limit of detection” is to be calculated as— three times the relative within batch standard deviation of a natural sample containing a low concentration of the parameter or substance; or five times the relative within batch standard deviation of a blank sample; - “precision” (the random error) is the standard deviation (within a batch and between batches) of the spread of results about the mean; and - “trueness” (the systematic error) is the difference between the mean value of a large number of repeated measurements and the true value.

(1) (2) (3) (4) (5) (6)
Organism or substance Concentration or value and unit of measurement Volume of water supplied m³/d Annual sampling frequency Estimated population of water supply zone Annual sampling frequency
* where the water originates from, or is influenced by, surface waters * where the water originates from, or is influenced by, surface waters * where the water originates from, or is influenced by, surface waters * where the water originates from, or is influenced by, surface waters * where the water originates from, or is influenced by, surface waters * where the water originates from, or is influenced by, surface waters
Benzene 1.0μg/l
Bromate 1.0μgBrO₃/l
≤999 S2 or R1 ≤4,999 S2 or R1
Clostridium perfringens[^f01030] (Including spores) 0 1,000—49,999 S4 or R1 5,000—50,000 S4 or R1
≤50,000
Number/ 100ml S8 or R2
1,2 dichloroethane 3.0 μg/l
Enterococci 0 Number/100ml
Nitrite 0.10 mgNO₂/l
(1) (2) (3) (4) (5)
--- --- --- --- ---
Parameter or other substance Concentration and unit of measurement Trueness % of concentration Precision % of concentration Limit of detection % of concentration
* Trueness, precision and limit of detection apply to the individual substances specified at 50% of the concentration in column (2). * Trueness, precision and limit of detection apply to the individual substances specified at 50% of the concentration in column (2). * Trueness, precision and limit of detection apply to the individual substances specified at 50% of the concentration in column (2). * Trueness, precision and limit of detection apply to the individual substances specified at 50% of the concentration in column (2). * Trueness, precision and limit of detection apply to the individual substances specified at 50% of the concentration in column (2).
Antimony 5.0 μgSb/l 25 25 25
Arsenic 10 μgAs/l 10 10 10
Benzene 1.0 μg/l 25 25 25
Boron 1.0 mgB/l 10 10 10
Bromate 10 μBrO₃/l 25 25 25
Copper 2.0 mgCu/l 10 10 10
1,2 dichloroethane 3.0 μg/l 25 25 10
Lead 25 μgPb/l 10 10 10
Nickel 20 μgNi/l 10 10 10
Nitrite (ex works) 0.1 gNO₂/l 10 10 10
Tetrachloroethene[^f01031]) Trichloroethene[^f01031] ) 10 μg/l 25 25 10

SCHEDULE 6 — PROGRAMMES OF WORK

A water undertaker’s programme of work shall—

TABLE

Signed

Signed on behalf of the National Assembly for Wales under section 66(1) of the Government of Wales Act 1998 .

Rhodri Morgan — First Secretary — 2001-12-07

Explanatory note

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Footnotes

[^f00001]: 1991 c. 56. Section 213 is amended by the Competition and Service (Utilities) Act 1992 (c. 43). Functions under section 67 of the Water Industry Act 1991 for making regulations concerning water supplied by water undertakers, and functions under section 69 of that Act were transferred to the National Assembly for Wales in relation to any water undertaker whose area is wholly or mainly in Wales by the National Assembly for Wales (Transfer of Functions) Order 1999 (S.I. 1999/672), Schedule 1, as substituted by S.I. 2000/253, Schedule 3. Functions under section 213 of the Water Industry Act 1991 are exercisable by the National Assembly for Wales to the same extent as the powers, duties and other provisions to which that section applies are exercisable by the Assembly; see S.I. 1999/672, Schedule 1, as substituted by S.I. 2000/253, Schedule 3.

[^f00002]: Functions under section 77(3) and (4) of the Water Industry Act 1991 are transferred to the National Assembly for Wales, so far as exercisable in relation to Wales, by S.I. 1999/672, Schedule 1, as substituted by S.I. 2000/253, Schedule 3.

[^f00003]: S.I. 1989/1147, amended by S.I. 1989/1384, 1991/1837, and 2790, 1996/3001 and 1999/1524.

[^f00004]: 1991 c. 57.

[^f00005]: 1977 c. 49. Section 8 was substituted by the Health Authorities Act 1995 (c. 17), section 1.

[^f00006]: See, as to the functions of customer services committees, section 29 of the Water Industry Act 1991.

[^f00007]: O.J. L330, 5.12.98, p.32.

[^f00008]: O.J. No. L194, 16.6.75, p.26.

[^f00009]: 1991 c. 57.

[^f00010]: S.I. 1996/3001.

[^f00011]: Regulations 23A and 23B were inserted by S.I. 1999/1524.

[^f00012]: The date on which regulation 23A of the Water Supply (Water Quality) Regulations 1989 came into force.

[^f00013]: O.J. No. L40, 11.2.89, p.12.

[^f00014]: Cmnd 2073.

[^f00015]: Cmnd 2183.

[^f00016]: O.J. No. L204, 21.7.98, p.37, amended by Council Directive 98/48/EC (O.J. No. L217, 5.8.98, p.18).

[^f00017]: As to the application of section 77(1) to the councils of counties in which there are no distinct councils see regulation 5(7) of S.I. 1994/867 as substituted by S.I. 1996/611.

[^f00018]: S.I. 1999/1524.

[^f00019]: S.I. 1989/1384.

[^f00020]: S.I. 1991/1837.

[^f00021]: S.I. 1991/2790, to which there are amendments not relevant to these Regulations.

[^f00022]: S.I. 1996/3001.

[^f00023]: 1998 c. 38.

Item Parameters Concentration or Value (maximum) Units of Measurement Point of compliance
1. Enterococci 0 number/100ml Consumers’ taps
2. Escherichia coli (E. coli) 0 number/100ml Consumers’ taps
Item Parameters Concentration or Value (maximum) Units of Measurement Point of compliance
--- --- --- --- ---
1. Coliform bacteria 0 number/100ml Service reservoirs* and water treatment works
2. Escherichia coli (E. coli) 0 number/100ml Service reservoirs and water treatment works

Note: *Compliance required as to 95% of samples from each service reservoir (regulation 4(6)).

Item Parameters Concentration or Value (maximum) Units of Measurement Point of compliance
1. Acrylamide 0.10 ℞g/l (i)
2. Antimony 5.0 ℞gSb/l Consumers’ taps
3. Arsenic 10 ℞gAs/l Consumers’ taps
4. Benzene 1.0 ℞g/l Consumers’ taps
5. Benzo(a)pyrene 0.010 ℞g/l Consumers’ taps
6. Boron 1.0 mgB/l Consumers’ taps
7. Bromate 10 ℞gBrO₃/l Consumers’ taps
8. Cadmium 5.0 ℞gCd/l Consumers’ taps
9. Chromium 50 ℞gCr/l Consumers’ taps
10. Copper(i) 2.0 mgCu/l Consumers’ taps
11. Cyanide 50 ℞gCN/l Consumers’ taps
12. 1, 2 dichloroethane 3.0 ℞g/l Consumers’ taps
13. Epichlorohydrin 0.10 ℞g/l (i)
14. Fluoride 1.5 mgF/l Consumers’ taps
15. Lead(ii) (a)25, from 25th December 2003 until immediately before 25th December 2013 ℞gPb/l Consumers’ taps
(b)10, on and after 25th December 2013 ℞gPb/l Consumers’ taps
16. Mercury 1.0 ℞gHg/l Consumers’ taps
17. Nickel(ii) 20 ℞gNi/l Consumers’ taps
18. Nitrate(iii) 50 mgNO₃/l Consumers’ taps
19. Nitrite(iii) 0.50 mgNO₂/l Consumers’ taps
0.10 Treatment Works
20. Pesticides(iv)(v)Aldrin )Dieldrin )Heptachlor )Heptachlor )epoxide ) 0.030 ℞g/l Consumers’ taps
other pesticides 0.10 ℞g/l Consumers’ taps
21. Pesticides: Total(vi) 0.50 ℞g/l Consumers’ taps
22. Polycyclic aromatic hydrocarbons(vii) 0.10 ℞g/l Consumers’ taps
23. Selenium 10 ℞gSe/l Consumers’ taps
24. Tetrachloroethene and Trichloroethene(viii) 10 ℞g/l Consumers’ taps
25. Trihalomethanes: Total(ix) 100 ℞g/l Consumers’ taps
26. Vinyl chloride 0.50 ℞g/l (i)

Notes:

Item Parameters Specification Concentration or Value (maximum unless otherwise stated) or State Units of Measurement Point of monitoring
1. Ammonium 0.50 mgNH₄/l Consumers’ taps
2. Chloride(i) 250 mgCl/l Supply point*
3. Clostridium perfringens (including spores) 0 Number/100ml Supply point*
4. Coliform bacteria 0 Number/100ml Consumers’ taps
5. Colony counts No abnormal change Number/1ml at 22°C Consumers’ taps, service
Number/1ml at 37°C Reservoirs and treatment works
6. Conductivity(i) 2500 ℞S/cm at 20°C Supply point*
7. Hydrogen ion 9.5 pHvalue Consumers’ taps
6.5 (minimum) pH value
8. Sulphate(i) 250 mgSO₄ /l Supply point*
9. Total indicative dose (for radioactivity)(ii) 0.10 mSv/year Supply point*
10. Total organic carbon (TOC) No abnormal change mgC/l Supply point*
11. Tritium (for radioactivity) 100 Bq/l Supply point*
12. Turbidity 1 NTU Treatment works

Notes:

*May be monitored from samples of water leaving treatment works or other supply point, as no significant change during distribution.

(1) (2) (3)
Item Parameter Circumstances
1. Aluminium When used as flocculant or where the water originates from, or is influenced by, surface waters
2. Ammonium
3. Clostridium perfringens (including spores) Where the water originates from, or is influenced by, surface waters
4. Coliform bacteria
5. Colony counts
6. Colour
7. Conductivity
8. Escherichia coli (E. coli)
9. Hydrogen ion
10. Iron When used as flocculant or where the water originates from, or is influenced by, surface waters
11. Manganese Where the water originates from, or is influenced by, surface waters
12. Nitrate When chloramination is practised
13. Nitrite When chloramination is practised
14. Odour
15. Taste
16. Turbidity
(1) (2) (3)
--- --- ---
Substances and parameters subject to check monitoring Estimated population of water supply zone Reduced
E. coli
Coliform bacteria <100
Residual disinfectant .100
Aluminium
Ammonium
Clostridium perfringens (including spores)* <100 1
100—4,999 2
5,000—9,999 6
Colony counts 10,000—29,999 12
Colour 30,000—49,999 18
Conductivity* 50,000—79,999 26
Hydrogen ion 80,000—100,000 38
Iron
Manganese
Nitrate(ii)
Nitrite(ii)
Odour
Taste
Turbidity
Parameters subject to audit monitoring
Aluminium
Antimony
Arsenic
Benzene* <100
Benzo(a)pyrene 100—4,999
Boron* 5,000—100,000
Bromate(iii)
Cadmium
Chromium
Clostridium perfringens (including spores)
Copper
Cyanide*
1,2 dichloroethane*
Enterococci
Fluoride*
Iron
Lead
Manganese
Mercury*
Nickel
Nitrate(ii)
Nitrite(ii)
Pesticides and related products*
Polycyclic aromatic <100
hydrocarbons 100—4,999
Selenium 5,000—100,000
Sodium
Trichloroethene
/Tetrachloroethene*
Tetrachloromethane*
Trihalomethanes
Chloride*
Sulphate*
Total organic carbon*
Tritium*
Gross alpha*(iv)
Gross beta*(iv)

Notes: * Sampling for these parameters may be within water supply zones or at supply points as specified in Table 3, subject to notes (ii) and (iii) below.

(1) (2) (3) (4) (5)
Item Substances and parameters Volume of water supplied m³/d Reduced Standard
1. E. Coli <20 4
2. Coliform bacteria 20—1,999 12 52
3. Colony counts 2,000—5,999 52 104
4. Nitrite(ii) 6,000—11,999 104 208
5. Residual disinfectant .12,000 104 365
6. Turbidity
Subject to check monitoring Subject to check monitoring
7. Clostridium perfringens(i) <20 2
20 — 999 2 4
8. Conductivity 1,000 — 1,999 6 12
2,000 — 5,999 12 24
6,000 — 9,999 18 36
10,000 — 15,999 26 52
16,000 — 32,999 52 104
33,000 — 49,999 78 156
50,000 — 67,999 104 208
68,000 — 84,999 130 260
85,000 — 101,999 156 312
102,000 —119,999 183 365
120,000 — 241,999 365 730
242,000 — 484,999 730 1,460
485,000 — 728,999 1,095 2,190
Subject to audit monitoring Subject to audit monitoring
9. Benzene
10. Boron
11. Bromate(iv)
11A Clostridium perfringens (including spores)
12. Cyanide
13. 1,2 dichloroethane
14. Fluoride
15. Mercury <20 1
16. Nitrite(iii) 20—999 4
17. Pesticides and Related products 1,000—49,999 8
50,000—89,999 12
90,000—299,999 24
300,000—649,000 36
18. Trichloroethene )Tetrachloroethene) .650,000 48
19. Tetrachloromethane
20. Chloride
21. Sulphate
22. Total organic carbon
23. Tritium
24. Gross alpha(v)
25. Gross beta(v)

Notes: *Sampling is at treatment works for the substances and parameters shown in column (1) of the Table as items 1 to 6 and at supply points for the other substances and parameters, except nitrite, subject to notes (ii) and (iii) below.

(1) (2)
Parameter Method
Clostridium perfringens (including spores) Membrane filtration followed by anaerobic incubation of the membrane on m-CP agar* at 44+ 1°C for 21+ 3 hours. Count opaque yellow colonies that turn pink or red after exposure to ammonium hydroxide vapours for 20 to 30 seconds.
Coliform bacteria ISO 9308-1
Colony count 22°C — enumeration of culturable microorganisms prEN ISO 6222
Colony count 37°C— enumeration of culturable microorganisms prEN ISO 6222
Enterococci ISO 7899-2
Escherichia coli (E. coli) ISO 9308-1

*The composition of m-CP agar is:

Basal medium
Tryptose 30.0g
Yeast extract 20.0g
Sucrose 5.0g
L-cysteine hydrochloride 1.0g
MgSO₄·7H₂O 0.1g
Bromocresol purple 40.0mg
Agar 15.0g
Water 1,000.0ml

Dissolve the ingredients of the basal medium, adjust pH to 7.6 and autoclave at 121°C for15 minutes. Allow the medium to cool and add:

D-cycloserine 400.0mg
Polymyxine-B sulphate 25.0mg
Indoxyl-[beta]-D-glucoside 60.0mg
to be dissolved in 8ml sterile water before addition
Filter — sterilised 0.5% phenolphthalein diphosphate solution 20.0ml
Filter — sterilised 4.5% FeCl₃· 6H₂O 2.0ml
(1) (2)
--- ---
Parameters Trueness % of prescribed concentration or value or specification
Aluminium 10
Ammonium 10
Antimony 25
Arsenic 10
Benzene 25
Benzo(a)pyrene 25
Boron 10
Bromate 25
Cadmium 10
Chloride 10
Chromium 10
Colour 10
Conductivity 10
Copper 10
Cyanide(i) 10
1,2-dichloroethane 25
Fluoride 10
Iron 10
Lead 10
Manganese 10
Mercury 20
Nickel 10
Nitrate 10
Nitrite 10
Pesticides and related products(ii) 25
Polycyclic aromatic hydrocarbons(iii) 25
Selenium 10
Sodium 10
Sulphate 10
Tetrachloromethane 20
Trichloroethene(iv) 25
Trihalomethanes: Total(iii) 25
Turbidity(v) 10
Turbidity(vi) 25

Notes:

The amendments to the 1989 Regulations referred to in regulation 40 are—

(13A) (1) Subject to paragraphs (5) and (6), in each of the years 2002 and 2003, a water undertaker shall take, or cause to be taken, from its sampling points or, as the case may be, its supply points, for analysis for testing against the concentrations and values specified in column (2) of Table 4A for the organisms and substances listed in column (1) of that Table, not less than the number of samples specified in paragraphs (2) and (3). (2) In respect of supply points and the supply of a volume of water within a range shown in column (3) of that Table, the number is that shown in column (4) of that Table with the prefix “S” as applicable to a volume within that range. (3) In respect of sampling points and the supply of water to an estimated population within a range shown in column (5) of that Table, the number is that shown in column (6) of that Table with the prefix “S” as applicable to a population within that range. (4) In each of those years samples shall be taken at regular intervals throughout the year. (5) Where— (a) a programme of work has been approved or is treated as approved under regulation 41 (transitional provision: programmes of work) of the Water Supply (Water Quality) Regulations 2001; or has otherwise been agreed by the National Assembly for Wales; and (b) at least one of the steps required to be taken in accordance with that programme— (i) relates to an organism or substance listed in column (1) of Table 4A; and (ii) remains to be completed, the number of samples to be taken in any period of twelve months beginning with the date on which the programe was approved, treated as approved, or agreed (as the case may be) and ending on the day on which the last of those steps is completed, for analysis for testing for that organism or substance, may be the number shown in column (4) or, as the case may be, column (6) of that Table with the prefix “R”. (6) Where analysis of the samples taken by a water undertaker in 2002 in accordance with this regulation has established a concentration or value in respect of an organism or substance listed in column (1) of Table 4A that is significantly lower than the prescribed concentration or value, the number of samples to be taken in 2003, for analysis for testing for that organism or substance, may be the number shown in column (4) or, as the case may be, column (6) of that Table with the prefix “R”.

(20A) The samples taken in accordance with regulation 13 shall additionally be tested against the concentrations and values specified in column (2) of Table 4B.

(3) In relation to each of the parameters and other substances listed in column (1) of Table 4B, paragraph (2)(d) shall have effect as if for sub-paragraph (iii) there were substituted the requirements of regulation 21A.

(21A) (1) The method of analysis used for testing for a parameter or other substance listed in column (1) of Table 4B against the concentrations in column (2) of that Table must be capable, at the time of use— (a) of measuring concentrations with the trueness and precision specified in relation to that parameter or substance in columns (3) and (4) of Table 4B; and (b) of detecting the parameter or substance at the limit of detection specified in relation to it in column (5) of that Table. (2) For the purposes of paragraph (1)— - “limit of detection” is to be calculated as— 1. three times the relative within batch standard deviation of a natural sample containing a low concentration of the parameter or substance; or 2. five times the relative within batch standard deviation of a blank sample; - “precision” (the random error) is the standard deviation (within a batch and between batches) of the spread of results about the mean; and - “trueness” (the systematic error) is the difference between the mean value of a large number of repeated measurements and the true value.

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