The Air Quality Limit Values (Wales) Regulations 2002

Type Welsh-Statutory-Instrument
Publication 2002-12-17
Last updated 2005-04-30
State In force
Jurisdiction Wales
Department King's Printer of Acts of Parliament
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articles Not indexed
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Made: 17th December 2002

Coming into force: 31st December 2002

The National Assembly for Wales ( “the National Assembly"), in exercise of the powers conferred upon it by section 29 of the Government of Wales Act 1998 and subsection (2) of section 2 of the European Communities Act 1972, and having been designated for the purpose of that subsection by Article 2 of the European Communities (Designation) (No. 3) Order 2000 in relation to measures relating to the assessment and management of ambient air quality and compliance with air quality limit values, target values and objectives, hereby makes the following Regulations:

Citation, commencement and application

1

Definitions

2

In these Regulations—

Responsibility for implementation of the Air Framework Directive

3

For the purposes of Article 3 (implementation and responsibilities) of Council Directive 96/62/EC on ambient air quality assessment and management the National Assembly is the competent authority in Wales responsible for—

Duty to ensure that ambient air quality is improved

4

Assessment of ambient air quality

5

The National Assembly must ensure that ambient air quality is assessed in each zone in relation to each of the relevant pollutants in accordance with regulations 6 to 8.

Classification of zones

6

Review of classifications

7

Method of assessment of ambient air quality

8

are set out in Schedule 6, and these methods must be used unless other methods are used which the National Assembly considers can be demonstrated to give equivalent results or, in relation to the sampling and measurement of PM10, which the National Assembly considers can be demonstrated to display a consistent relationship to the reference method.

Action plans

9

Action to be taken where limit values are exceeded

10

Zones where the levels are lower than the limit value

11

Public information

12

Revocations of Air Quality Limit Values (Wales) Regulations 2001 and Air Quality Standards Regulations 1989 and transitional provisions

13

that action is to be treated, for the purpose of these Regulations, as having been taken under these Regulations.

SCHEDULE 1 — LIMIT VALUES, MARGINS OF TOLERANCE ETC.

PART I — SULPHUR DIOXIDE

Limit values for sulphur dioxide

1.1

Averaging period Limit value Margin of tolerance[^f00013] Date by which limit value is to be met
1 Hourly limit value for the protection of human health 1 hour 350 μg/m³, not to be exceeded more than 24 times a calendar year 60 μg/m³ on 1st January 2003, reducing on 1st January of each following year by equal annual amounts to reach 0 μg/m³ by 1st January 2005 1st January 2005
2 Daily limit value for the protection of human health 24 hours 125 μg/m³, not to be exceeded more than 3 times a calendar year None 1st January 2005
3 Limit value for the protection of ecosystems Calendar year and winter (1st October to 31st March) 20 μg/m³ None

Alert threshold for sulphur dioxide

1.2

500 μg/m3 measured over three consecutive hours at locations representative of air quality over at least 100 km² or an entire zone or agglomeration, whichever is the smaller.

Minimum details to be made available to the public when the alert threshold for sulphur dioxide is exceeded

1.3

Details to be made available to the public should include at least:

PART II — NITROGEN DIOXIDE (NO2) AND OXIDES OF NITROGEN (NOx)

Limit values for nitrogen dioxide and oxides of nitrogen

2.1

Averaging period Limit value Margin of tolerance Date by which limit value is to be met
1 Hourly limit value for the protection of human health 1 hour 200 μg/m³ NO₂, not to be exceeded more than 18 times a calendar year 70 μg/m³ on 1st January 2003, reducing on 1st January of each following year by equal annual amounts to reach 0 μg/m³ by 1st January 2010 1st January 2010
2 Annual limit value for the protection of human health Calendar year 40 μg/m³ NO₂ 14 μg/m³ on 1st January 2003, reducing on 1st January of each following year by equal annual amounts to reach 0 μg/m³ by 1st January 2010 1st January 2010
3 Annual limit value for the protection of vegetation Calendar year 30 μg/m³ NOx None

Alert threshold for nitrogen dioxide

2.2

400 μg/m3 measured over three consecutive hours at locations representative of air quality over at least 100 km² or an entire zone or agglomeration, whichever is the smaller.

Minimum details to be made available to the public when the alert threshold for nitrogen dioxide is exceeded

2.3

Details to be made available to the public should include at least:

PART III — PARTICULATE MATTER (PM10)

1

24-hour limit value for the protection of human health

2

Annual limit value for the protection of human health

PART IV — LEAD

Averaging period Limit value Margin of tolerance Date by which limit value is to be met
Annual limit value for the protection of human health Calendar year 0.5μg/m³ 0.2μg/m³ on 1st January 2003, reducing on 1st January of each following year by equal annual amounts to reach 0μg/m³ by 1st January 2005 1st January 2005

PART V — BENZENE

Averaging period Limit value Margin of tolerance Date by which limit value is to be met
Limit value for the protection of human health Calendar year 5μg/m³ 5μg/m³ on 1st January 2003, reducing on 1st January 2006 and every 12 months thereafter by 1μg/m³ to reach 0μg/m³ by 1st January 2010 1st January 2010

PART VI — CARBON monoxide

Averaging period Limit value Margin of tolerance Date by which limit value is to be met
The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day. The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day. The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day. The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day. The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day.
Limit value for the protection of human health Maximum daily 8-hour mean 10mg/m³ 4 mg/m³ on 1st January 2003, reducing every 12 months thereafter by 2 mg/m³ to reach 0 mg/m³ by 1 January 2005 1 January 2005

SCHEDULE 2 — UPPER AND LOWER ASSESSMENT THRESHOLDS AND EXCEEDANCES

PART I — Upper and lower assessment thresholds

The following upper and lower assessment thresholds will apply:

SULPHUR DIOXIDE a Health protectionEcosystem protection Upper assessment threshold60% of 24-hour limit value (75 μg/m³, not to be exceeded more than 3 times in any calendar year)60% of winter limit value (12 μg/m³)Lower assessment threshold40% of 24-hour limit value (50 μg/m³), not to be exceeded more than 3 times in any calendar year)40% of winter limit value (8 μg/m³)

NITROGEN DIOXIDE AND OXIDES OF NITROGEN b Hourly limit value for the protection of human health (NO₂)Annual limit value for the protection of human health (NO₂)Annual limit value for the protection of vegetation (NOx) Upper assessment value70% of limit value (140 μg/m³, not to be exceeded more than 18 times in any calendar year)80% of limit value (32 μg/m³)80% of limit value (24 μg/m³)Lower assessment value50% of limit value (100 μg/m³, not to be exceeded more than 18 times in any calendar year).65% of limit value (26 μg/m³)65% of limit value (19.5 μg/m³)

PARTICULATE MATTER[^f00014] c 24-hour averageAnnual average Upper assessment threshold60% of limit value (30 μg/m³, not to be exceeded more than seven times in any calendar year).70% of limit value (14 μg/m³)Lower assessment threshold40% of limit value (20 μg/m³, not to be exceeded more than seven times in any calendar year).50% of limit value (10 μg/m³)

LEAD d Annual average Upper assessment threshold70% of limit value (0.35 μg/m³)Lower assessment threshold50% of limit value (0.25 μg/m³)

BENZENE e Annual average Upper assessment threshold70% of limit value (3.5 μg/m³)Lower assessment threshold40% of limit value (2 μg/m³)

CARBON monoxide f Eight-hour average Upper assessment threshold70% of limit value (7 mg/m³)Lower assessment threshold50% of limit value (5 mg/m³)

PART II — Determination of exceedances of upper and lower assessment thresholds

Exceedances of upper and lower assessment thresholds must be determined on the basis of concentrations during the previous five years where sufficient data are available. An assessment threshold will be deemed to have been exceeded if it has been exceeded during at least three separate years out of the previous five years.

Where fewer than five years' data are available, measurement campaigns of short duration during the period of the year and at locations likely to be typical of the highest pollution levels may be combined with results obtained from emission inventories and modelling to determine exceedances of the upper and lower assessment thresholds.

SCHEDULE 3 — LOCATION OF SAMPLING POINTS FOR THE MEASUREMENT OF RELEVANT POLLUTANTS IN AMBIENT AIR

The following considerations will apply to fixed measurement.

PART I — Macroscale siting

Protection of human health a Sampling points directed at the protection of human health should be sited: i to provide data on the areas within zones and agglomerations where the highest concentrations occur to which the population is likely to be directly or indirectly exposed for a period which is significant in relation to the averaging period of the limit value(s); ii to provide data on levels in other areas within the zones and agglomerations which are representative of the exposure of the general population. Sampling points should in general be sited to avoid measuring very small micro-environments in their immediate vicinity. As a guideline, a sampling point should be sited to be representative of air quality in a surrounding area of no less than 200 m² at traffic-orientated sites and of several square kilometres at urban-background sites. Sampling points should also, where possible, be representative of similar locations not in their immediate vicinity. Account should be taken of the need to locate sampling points on islands, where that is necessary for the protection of human health.

Protection of ecosystems and vegetation b Sampling points targeted at the protection of ecosystems or vegetation should be sited more than 20 km from agglomerations or more than 5 km from other built-up areas, industrial installations or motorways. As a guideline, a sampling point should be sited to be representative of air quality in a surrounding area of at least 1000 km². A sampling point may be sited at a lesser distance or to be representative of air quality in a less extended area, taking account of geographical conditions. Account should be taken of the need to assess air quality on islands.

PART II — Microscale siting

The following guidelines should be met as far as practicable:

The following factors may also be taken into account:

PART III — Documentation and review of site selection

The site-selection procedures should be fully documented at the classification stage by such means as compass-point photographs of the surrounding area and a detailed map. Sites should be reviewed at regular intervals with repeated documentation to ensure that selection criteria remain valid over time.

SCHEDULE 4 — CRITERIA FOR DETERMINING MINIMUM NUMBERS OF SAMPLING POINTS FOR FIXED MEASUREMENT OF CONCENTRATIONS OF RELEVANT POLLUTANTS IN AMBIENT AIR

PART I — Minimum number of sampling points for fixed measurement to assess compliance with limit values for the protection of human health and alertthresholds in zones and agglomerations where fixed measurement is the sole source of information

Diffuse sources a Population of zone (thousands)If concentrations exceed the upper assessment thresholdsIf maximum concentrations are between the upper and lower assessment thresholdsFor SO₂ and NO₂ in agglomerations where maximum concentrations are below the lower assessment threshold 0 —25011not applicable250 —499211500 —749211750 —9993111,000 —1,4994211,500 —1,9995212,000 —2,7496322,750 —3,7497323,750 —4,7498424,750 —5,999942>6,0001053For NO₂ and particulate matter: to include at least one urban-background station and one traffic-orientated station — this requirement shall also apply to benzene and carbon monoxide provided that it does not increase the number of sampling points.

Point sources b For the assessment of pollution in the vicinity of point sources, the number of sampling points for fixed measurement should be calculated taking into account emission densities, the likely distribution patterns of ambient-air pollution and the potential exposure of the population.

PART II — Minimum number of sampling points for fixed measurements to assess compliance with limit values for the protection of ecosystems or vegetation in zones other than agglomerations

If maximum concentrations exceed the assessment threshold If maximum concentrations are between the upper and lower assessment thresholds
In island zones the number of sampling points for fixed measurement should be calculated taking into account the likely distribution patterns of ambient-air pollution and the potential exposure of ecosystems or vegetation. In island zones the number of sampling points for fixed measurement should be calculated taking into account the likely distribution patterns of ambient-air pollution and the potential exposure of ecosystems or vegetation.
1 station every 20,000 km² 1 station every 40,000 km²

SCHEDULE 5 — DATA-QUALITY OBJECTIVES AND COMPILATION OF RESULTS OF AIR-QUALITY ASSESSMENT

PART I — Data-quality objectives

The following data-quality objectives for the required accuracy of assessment methods, of minimum time coverage and of data capture of measurement are laid down to guide quality-assurance programmes.

Sulphur dioxide, nitrogen dioxide and oxides of nitrogen Particulate matter and lead
The accuracy of the measurement is defined as laid down in the “Guide to the Expression of Uncertainty of Measurements ” (ISO 1993)[^f00015] or in ISO 5725-1 “Accuracy (trueness and precision) of measurement methods and results ” (ISO 1994)[^f00016]. The percentages in the table are given for individual measurements averaged, over the period considered, by the limit value, for a 95% confidence interval (bias + two times the standard deviation). The accuracy for continuous measurements should be interpreted as being applicable in the region of the appropriate limit value. The accuracy for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered by the limit value, without taking account the timing of the events. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or the normal maintenance of the instrumentation. The National Assembly may allow for random measurements to be made instead of continuous measurements for particulate matter and lead by methods for which accuracy within the 95% confidence interval with respect to continuous monitoring has been demonstrated to be within 10%. Random sampling must be spread evenly over the year. The accuracy of the measurement is defined as laid down in the “Guide to the Expression of Uncertainty of Measurements ” (ISO 1993)[^f00015] or in ISO 5725-1 “Accuracy (trueness and precision) of measurement methods and results ” (ISO 1994)[^f00016]. The percentages in the table are given for individual measurements averaged, over the period considered, by the limit value, for a 95% confidence interval (bias + two times the standard deviation). The accuracy for continuous measurements should be interpreted as being applicable in the region of the appropriate limit value. The accuracy for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered by the limit value, without taking account the timing of the events. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or the normal maintenance of the instrumentation. The National Assembly may allow for random measurements to be made instead of continuous measurements for particulate matter and lead by methods for which accuracy within the 95% confidence interval with respect to continuous monitoring has been demonstrated to be within 10%. Random sampling must be spread evenly over the year. The accuracy of the measurement is defined as laid down in the “Guide to the Expression of Uncertainty of Measurements ” (ISO 1993)[^f00015] or in ISO 5725-1 “Accuracy (trueness and precision) of measurement methods and results ” (ISO 1994)[^f00016]. The percentages in the table are given for individual measurements averaged, over the period considered, by the limit value, for a 95% confidence interval (bias + two times the standard deviation). The accuracy for continuous measurements should be interpreted as being applicable in the region of the appropriate limit value. The accuracy for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered by the limit value, without taking account the timing of the events. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or the normal maintenance of the instrumentation. The National Assembly may allow for random measurements to be made instead of continuous measurements for particulate matter and lead by methods for which accuracy within the 95% confidence interval with respect to continuous monitoring has been demonstrated to be within 10%. Random sampling must be spread evenly over the year.
Continuous measurement
Accuracy 15% 25%
Minimum data capture 90% 90%
Indicative measurement
Accuracy 25% 50%
Minimum data capture 90% 90%
Minimum time coverage 14% (One measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year.) 14% (One measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year.)
Modelling
Accuracy:
Hourly averages 50%—60%
Daily averages 50%
Annual averages 30% 50%
Objective estimation
Accuracy: 75% 100%

The following data quality objectives, for allowed uncertainty of assessment methods, and of minimum time coverage and of data capture of measurement are provided to guide quality assurance programmes.

Benzene Carbon monoxide
The uncertainty (on a 95% confidence interval) of the assessment methods shall be evaluated in accordance with the “Guide to the Expression of Uncertainty of Measurements” (ISO 1993)[^f00017] or the methodology of ISO 5725:1994[^f00018]. The percentages for uncertainty in the above table are given for individual measurements averaged over the period considered by the limit value, for a 95% confidence interval. The uncertainty for the fixed measurements should be interpreted as being applicable in the region of the appropriate limit value. The uncertainty for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered, by the limit value, without taking into account the timing of the events. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration of the normal maintenance of the instrumentation. The National Assembly may allow for random measurements to be made instead of continuous measurements for benzene if the uncertainty, including the uncertainty due to random sampling, meets the quality objective of 25%. Random sampling must be spread evenly across the year. The uncertainty (on a 95% confidence interval) of the assessment methods shall be evaluated in accordance with the “Guide to the Expression of Uncertainty of Measurements” (ISO 1993)[^f00017] or the methodology of ISO 5725:1994[^f00018]. The percentages for uncertainty in the above table are given for individual measurements averaged over the period considered by the limit value, for a 95% confidence interval. The uncertainty for the fixed measurements should be interpreted as being applicable in the region of the appropriate limit value. The uncertainty for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered, by the limit value, without taking into account the timing of the events. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration of the normal maintenance of the instrumentation. The National Assembly may allow for random measurements to be made instead of continuous measurements for benzene if the uncertainty, including the uncertainty due to random sampling, meets the quality objective of 25%. Random sampling must be spread evenly across the year. The uncertainty (on a 95% confidence interval) of the assessment methods shall be evaluated in accordance with the “Guide to the Expression of Uncertainty of Measurements” (ISO 1993)[^f00017] or the methodology of ISO 5725:1994[^f00018]. The percentages for uncertainty in the above table are given for individual measurements averaged over the period considered by the limit value, for a 95% confidence interval. The uncertainty for the fixed measurements should be interpreted as being applicable in the region of the appropriate limit value. The uncertainty for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered, by the limit value, without taking into account the timing of the events. The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration of the normal maintenance of the instrumentation. The National Assembly may allow for random measurements to be made instead of continuous measurements for benzene if the uncertainty, including the uncertainty due to random sampling, meets the quality objective of 25%. Random sampling must be spread evenly across the year.
Fixed measurements
Uncertainty 25% 15%
Minimum data capture 90% 90%
Minimum time coverage 35% urban background and traffic sites (distributed over the year to be representative of various conditions for climate and traffic) 90% industrial sites
Indicative measurements
Uncertainty 30% 25%
Minimum data capture 90% 90%
Minimum time coverage 14% (one day’s measurement a week at random, evenly distributed over the year, or 8 weeks evenly distributed over the year) 14% (one measurement a week at random, evenly distributed over the year, or 8 weeks evenly distributed over the year)
Modelling
Uncertainty:
Eight-hour averages 50%
Annual averages 50%
Objective estimation
Uncertainty 100% 75%

PART II — Results of air quality assessment

The following information should be compiled for zones and agglomerations within which sources other than measurement are employed to supplement information from measurement or as the sole means of air quality assessment:

Where possible maps shall be compiled showing concentration distributions within each zone and agglomeration.

SCHEDULE 6 — REFERENCE METHODS FOR ASSESSMENT OF CONCENTRATIONS OF RELEVANT POLLUTANTS

PART I — Reference method for the analysis of sulphur dioxide

ISO/FDIS 10498 (Standard in draft) Ambient air — determination of sulphur dioxide — ultraviolet fluorescence method[^f00019].

PART II — Reference method for the analysis of nitrogen dioxide and oxides of nitrogen

ISO 7996: 1985 Ambient air — determination of the mass concentrations of nitrogen oxides — chemiluminescence method[^f00020].

PART IIIA — Reference method for the sampling of lead

The reference method for the sampling of lead will be that described in the Annex to Directive 82/884/EEC[^f00021] until such time as the limit value in Schedule 1 to these Regulations is to be met, when the reference method will be that for PM₁₀ specified in Part IV of this Schedule.

PART IIIB — Reference method for the analysis of lead

ISO 9855: 1993 Ambient air — Determination of the particulate lead content of aerosols collected in filters. Atomic absorption spectroscopy method[^f00022].

PART IV — Reference method for the sampling and measurement of PM10

The reference method for the sampling and measurement of PM₁₀ will be that described in EN 12341 “ Air Quality — Field Test Procedure to Demonstrate Reference Equivalence of Sampling Methods for the PM₁₀ fraction of particulate matter” [^f00023]. The measurement principle is based on the collection on a filter of the PM₁₀ fraction of ambient particulate matter and the gravimetric mass determination.

PART V — Reference method for the sampling and analysis of benzene

The reference method for the measurement of benzene will be pumped sampling on a sorbent cartridge followed by gas chromatographic determination.

PART VI — Reference method for the analysis of carbon monoxide

The reference method for the measurement of carbon monoxide will be a method based on the non-dispersive infra-red spectrometric (NDIR) method.

SCHEDULE 7 — INFORMATION TO BE INCLUDED IN THE PLAN OR PROGRAMME FOR IMPROVEMENT OF AIR QUALITY

Localisation of excess pollution

1

General information

2

Responsible authorities

3

Nature and assessment of pollution

4

Origin of pollution

5

Analysis of the situation

6

Details of those measures or projects for improvement which existed prior to 21st November 1996

7

Details of those measures or projects adopted with a view to reducing pollution following 21st November 1996

8

Details of the measures or projects planned or being researched for the long term.

9

List of the publications, documents, work etc used to supplement information requested in this Schedule.

10

Signed

Signed on behalf of the National Assembly for Wales under section 66(1) of the Government of Wales Act 1998

D. Elis-Thomas — The Presiding Officer of the National Assembly — 2002-12-17

Explanatory note

(This note is not part of the Regulations)

1Provisions conferring power on local authorities—

aconcerning “local air quality management" under Part IV of the Environment Act 1995 (c.25);

bfor control of smoke emissions under the Clean Air Act 1993 (c.11);

cfor taking account of air quality issues when making land use planning and transport plans;

dfor the control of traffic growth and management, under the Road Traffic Reduction Act 1997 (c.54), the Road Traffic Regulation Act 1984 (c.27) and the Road Traffic Act 1991 (c.40).

2Control of industrial emissions—

aby local authorities by means of “local air pollution control" and by the Environment Agency under “integrated pollution control" under Part I of the Environmental Protection Act 1990 (c.43);

bby the Environment Agency and local authorities using “integrated pollution prevention and control" under the Pollution Prevention and Control Act 1999 (c.24) and the Pollution Prevention and Control (England and Wales) Regulations 2000 (S.I. 2000/1973).

3Control of transport emissions

Footnotes

[^f00001]: 1998 c. 38.

[^f00002]: 1972 c. 68.

[^f00003]: S.I. 2000/2812.

[^f00004]: OJ No L296, 21.11.96, p. 55.

[^f00005]: See regulation 10(8).

[^f00006]: See regulation 10(10).

[^f00007]: See regulation 10(11).

[^f00008]: Regulation 9(3) of the Air Quality Limit Values (Wales) Regulations 2001 imposed a corresponding obligation to prepare a plan or programme for the attainment of the relevant limit values, in relation to these pollutants, by dates prior to the coming into force of these Regulations.

[^f00009]: S.I. 2001/2683 (W.224).

[^f00010]: S.I. 1989/317, amended by S.I. 1995/3146 and partially revoked, in relation to Wales, by S.I. 2001/2683 (W. 224).

[^f00011]: OJ L229, 30.8.1980, p.30.

[^f00012]: 1998 c. 38.

[^f00013]: The figures for Margins of Tolerance for each of the relevant pollutants given in this Schedule are calculated from those given in Annex I of Directive 99/30/EC and Annexes I and II of Directive 2000/69/EC.

[^f00014]: The upper and lower assessment thresholds for PM₁₀ are based on the indicative limit values for 1 January 2010, which will be reviewed in the light of further information on health and environmental effects, technical feasibility and experience in the application of the existing “Stage 1” limit values. See Article 10 of Directive 99/30/EC.

[^f00015]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” sales department either by telephone on 020-8996-9001 or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL.

[^f00016]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” as for footnote (a) above.

[^f00017]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” sales department either by telephone on 020-8996-9001 or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL.

[^f00018]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” as for footnote (a) above.

[^f00019]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” sales department either by telephone on 020-8996-9001 or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL.

[^f00020]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” as for footnote (a) above.

[^f00021]: OJ L378, 31.12.1982, p.15.

[^f00022]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI” sales department either by telephone on 020-8996-9001 or by post from the BSI Standards House, 389 Chiswick High Road, London W4 4AL.

[^f00023]: European Standards Institute “CEN” publication reference BSEN 12341, obtainable from the British Standards Institution “BSI” as for footnote (a) above.

1

1

500μg/m3 measured over three consecutive hours at locations representative of air quality over at least 100 km² or an entire zone or agglomeration, whichever is the smaller.

1

Details to be made available to the public should include at least:

2

2

400μg/m3 measured over three consecutive hours at locations representative of air quality over at least 100 km² or an entire zone or agglomeration, whichever is the smaller.

2

Details to be made available to the public should include at least:

Averaging period Limit value Margin of tolerance Date by which limit value is to be met
1.24-hour limit value for the protection of human health 24 hours 50μg/m³ PM₁₀, not to be exceeded more than 35 times a calendar year 10μg/m³ on 1st January 2003, reducing on 1st January of each following year by equal annual amounts to reach 0μg/m³ by 1st January 2005 1st January 2005
2.Annual limit value for the protection of human health Calendar year 40μ g/m³ PM₁₀ 3.2μg/m³ on 1st January 2003, reducing on 1st January of each following year by equal annual amounts to reach 0μg/m³ by 1st January 2005 1st January 2005
Averaging period Limit value Margin of tolerance Date by which limit value is to be met
--- --- --- --- ---
Limit value for the protection of human health Maximum daily 8-hour mean 10mg/m³ 4 mg/m³ on 1st January 2003, reducing every 12 months thereafter by 2 mg/m³ to reach 0 mg/m³ by 1 January 2005 1 January 2005

The maximum daily 8-hour mean concentration shall be selected by examining 8-hour running averages, calculated from hourly data and updated each hour. Each 8-hour average so calculated shall be assigned to the day on which it ends, i.e. the first calculation period for any one day shall be the period from 17:00 on the previous day to 01:00 on that day; the last calculation period for any one day shall be the period from 16:00 to 24:00 on that day.

The following upper and lower assessment thresholds will apply:

SULPHUR DIOXIDEa Health protectionEcosystem protectionUpper assessment threshold60% of 24-hour limit value (75μg/m³, not to be exceeded more than 3 times in any calendar year)60% of winter limit value (12μg/m³)Lower assessment threshold40% of 24-hour limit value (50μg/m³), not to be exceeded more than 3 times in any calendar year)40% of winter limit value (8μg/m³)

NITROGEN DIOXIDE AND OXIDES OF NITROGENb Hourly limit value for the protection of human health (NO₂)Annual limit value for the protection of human health (NO₂)Annual limit value for the protection of vegetation (NOx)Upper assessment value70% of limit value (140μg/m³, not to be exceeded more than 18 times in any calendar year)80% of limit value (32μg/m³)80% of limit value (24μg/m³)Lower assessment value50% of limit value (100μg/m³, not to be exceeded more than 18 times in any calendar year).65% of limit value (26μg/m³)65% of limit value (19.5μg/m³)

PARTICULATE MATTER c 24-hour averageAnnual averageUpper assessment threshold60% of limit value (30μg/m³, not to be exceeded more than seven times in any calendar year).70% of limit value (14μg/m³)Lower assessment threshold40% of limit value (20μg/m³, not to be exceeded more than seven times in any calendar year).50% of limit value (10μg/m³)

LEADd Annual averageUpper assessment threshold70% of limit value (0.35μg/m³)Lower assessment threshold50% of limit value (0.25μg/m³)

BENZENEe Annual averageUpper assessment threshold70% of limit value (3.5μg/m³)Lower assessment threshold40% of limit value (2μg/m³)

CARBON monoxidef Eight-hour averageUpper assessment threshold70% of limit value (7 mg/m³)Lower assessment threshold50% of limit value (5 mg/m³)

Exceedances of upper and lower assessment thresholds must be determined on the basis of concentrations during the previous five years where sufficient data are available. An assessment threshold will be deemed to have been exceeded if it has been exceeded during at least three separate years out of the previous five years.

Where fewer than five years’ data are available, measurement campaigns of short duration during the period of the year and at locations likely to be typical of the highest pollution levels may be combined with results obtained from emission inventories and modelling to determine exceedances of the upper and lower assessment thresholds.

The following considerations will apply to fixed measurement.

Protection of human healthaSampling points directed at the protection of human health should be sited:ito provide data on the areas within zones and agglomerations where the highest concentrations occur to which the population is likely to be directly or indirectly exposed for a period which is significant in relation to the averaging period of the limit value(s);iito provide data on levels in other areas within the zones and agglomerations which are representative of the exposure of the general population.Sampling points should in general be sited to avoid measuring very small micro-environments in their immediate vicinity. As a guideline, a sampling point should be sited to be representative of air quality in a surrounding area of no less than 200 m² at traffic-orientated sites and of several square kilometres at urban-background sites.Sampling points should also, where possible, be representative of similar locations not in their immediate vicinity.Account should be taken of the need to locate sampling points on islands, where that is necessary for the protection of human health.

Protection of ecosystems and vegetationbSampling points targeted at the protection of ecosystems or vegetation should be sited more than 20 km from agglomerations or more than 5 km from other built-up areas, industrial installations or motorways. As a guideline, a sampling point should be sited to be representative of air quality in a surrounding area of at least 1000 km². A sampling point may be sited at a lesser distance or to be representative of air quality in a less extended area, taking account of geographical conditions.Account should be taken of the need to assess air quality on islands.

The following guidelines should be met as far as practicable:

The following factors may also be taken into account:

The site-selection procedures should be fully documented at the classification stage by such means as compass-point photographs of the surrounding area and a detailed map. Sites should be reviewed at regular intervals with repeated documentation to ensure that selection criteria remain valid over time.

Diffuse sourcesa Population of zone (thousands)If concentrations exceed the upper assessment thresholdsIf maximum concentrations are between the upper and lower assessment thresholdsFor SO₂ and NO₂ in agglomerations where maximum concentrations are below the lower assessment threshold0 —25011not applicable250 —499211500 —749211750 —9993111,000 —1,4994211,500 —1,9995212,000 —2,7496322,750 —3,7497323,750 —4,7498424,750 —5,9999426,0001053For NO₂ and particulate matter: to include at least one urban-background station and one traffic-orientated station — this requirement shall also apply to benzene and carbon monoxide provided that it does not increase the number of sampling points.

Point sourcesbFor the assessment of pollution in the vicinity of point sources, the number of sampling points for fixed measurement should be calculated taking into account emission densities, the likely distribution patterns of ambient-air pollution and the potential exposure of the population.

If maximum concentrations exceed the assessment threshold If maximum concentrations are between the upper and lower assessment thresholds
1 station every 20,000 km² 1 station every 40,000 km²

In island zones the number of sampling points for fixed measurement should be calculated taking into account the likely distribution patterns of ambient-air pollution and the potential exposure of ecosystems or vegetation.

The following data-quality objectives for the required accuracy of assessment methods, of minimum time coverage and of data capture of measurement are laid down to guide quality-assurance programmes.

Sulphur dioxide, nitrogen dioxide and oxides of nitrogen Particulate matter and lead
Continuous measurement Continuous measurement Continuous measurement
Accuracy 15% 25%
Minimum data capture 90% 90%
Indicative measurement Indicative measurement Indicative measurement
Accuracy 25% 50%
Minimum data capture 90% 90%
Minimum time coverage 14% (One measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year.) 14% (One measurement a week at random, evenly distributed over the year, or eight weeks evenly distributed over the year.)
Modelling Modelling Modelling
Accuracy:
Hourly averages 50%—60%
Daily averages 50%
Annual averages 30% 50%
Objective estimation Objective estimation Objective estimation
Accuracy: 75% 100%

The accuracy of the measurement is defined as laid down in the “Guide to the Expression of Uncertainty of Measurements" (ISO 1993) or in ISO 5725-1 “Accuracy (trueness and precision) of measurement methods and results" (ISO 1994) . The percentages in the table are given for individual measurements averaged, over the period considered, by the limit value, for a 95% confidence interval (bias + two times the standard deviation). The accuracy for continuous measurements should be interpreted as being applicable in the region of the appropriate limit value.

The accuracy for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered by the limit value, without taking account the timing of the events.

The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration or the normal maintenance of the instrumentation.

The National Assembly may allow for random measurements to be made instead of continuous measurements for particulate matter and lead by methods for which accuracy within the 95% confidence interval with respect to continuous monitoring has been demonstrated to be within 10%. Random sampling must be spread evenly over the year.

The following data quality objectives, for allowed uncertainty of assessment methods, and of minimum time coverage and of data capture of measurement are provided to guide quality assurance programmes.

Benzene Carbon monoxide
Fixed measurements Fixed measurements Fixed measurements
Uncertainty 25% 15%
Minimum data capture 90% 90%
Minimum time coverage 35% urban background and traffic sites (distributed over the year to be representative of various conditions for climate and traffic) 90% industrial sites
Indicative measurements Indicative measurements Indicative measurements
Uncertainty 30% 25%
Minimum data capture 90% 90%
Minimum time coverage 14% (one day’s measurement a week at random, evenly distributed over the year, or 8 weeks evenly distributed over the year) 14% (one measurement a week at random, evenly distributed over the year, or 8 weeks evenly distributed over the year)
Modelling Modelling Modelling
Uncertainty:
Eight-hour averages 50%
Annual averages 50%
Objective estimation Objective estimation Objective estimation
Uncertainty 100% 75%

The uncertainty (on a 95% confidence interval) of the assessment methods shall be evaluated in accordance with the “Guide to the Expression of Uncertainty of Measurements" (ISO 1993) or the methodology of ISO 5725:1994 . The percentages for uncertainty in the above table are given for individual measurements averaged over the period considered by the limit value, for a 95% confidence interval. The uncertainty for the fixed measurements should be interpreted as being applicable in the region of the appropriate limit value.

The uncertainty for modelling and objective estimation is defined as the maximum deviation of the measured and calculated concentration levels, over the period considered, by the limit value, without taking into account the timing of the events.

The requirements for minimum data capture and time coverage do not include losses of data due to the regular calibration of the normal maintenance of the instrumentation.

The National Assembly may allow for random measurements to be made instead of continuous measurements for benzene if the uncertainty, including the uncertainty due to random sampling, meets the quality objective of 25%. Random sampling must be spread evenly across the year.

The following information should be compiled for zones and agglomerations within which sources other than measurement are employed to supplement information from measurement or as the sole means of air quality assessment:

Where possible maps shall be compiled showing concentration distributions within each zone and agglomeration.

ISO/FDIS 10498 (Standard in draft) Ambient air — determination of sulphur dioxide — ultraviolet fluorescence method .

ISO 7996: 1985 Ambient air — determination of the mass concentrations of nitrogen oxides — chemiluminescence method .

The reference method for the sampling of lead will be that described in the Annex to Directive 82/884/EEC until such time as the limit value in Schedule 1 to these Regulations is to be met, when the reference method will be that for PM₁₀ specified in Part IV of this Schedule.

ISO 9855: 1993 Ambient air — Determination of the particulate lead content of aerosols collected in filters. Atomic absorption spectroscopy method .

The reference method for the sampling and measurement of PM₁₀ will be that described in EN 12341 “ Air Quality — Field Test Procedure to Demonstrate Reference Equivalence of Sampling Methods for the PM₁₀ fraction of particulate matter". The measurement principle is based on the collection on a filter of the PM₁₀ fraction of ambient particulate matter and the gravimetric mass determination.

The reference method for the measurement of benzene will be pumped sampling on a sorbent cartridge followed by gas chromatographic determination.

The reference method for the measurement of carbon monoxide will be a method based on the non-dispersive infra-red spectrometric (NDIR) method.

Editorial notes

[^c17958171]: 1998 c.38.

[^c17958181]: 1972 c.68.

[^c17958191]: S.I. 2000/2812.

[^c17958201]: OJ No L296, 21.11.96, p. 55.

[^c17958211]: See regulation 10(8).

[^c17958221]: See regulation 10(10).

[^c17958231]: See regulation 10(11).

[^c17958241]: Regulation 9(3) of the Air Quality Limit Values (Wales) Regulations 2001 imposed a corresponding obligation to prepare a plan or programme for the attainment of the relevant limit values, in relation to these pollutants, by dates prior to the coming into force of these Regulations.

[^c17958251]: S.I. 2001/2683 (W.224).

[^c17958261]: S.I. 1989/317, amended by S.I. 1995/3146 and partially revoked, in relation to Wales, by S.I. 2001/2683 (W. 224).

[^c17958271]: OJ L229, 30.8.1980, p.30.

[^c17958281]: 1998 c.38.

[^c17958291]: The figures for Margins of Tolerance for each of the relevant pollutants given in this Schedule are calculated from those given in Annex I of Directive 99/30/EC and Annexes I and II of Directive 2000/69/EC.

[^c17958301]: The upper and lower assessment thresholds for PM ₁₀ are based on the indicative limit values for 1 January 2010, which will be reviewed in the light of further information on health and environmental effects, technical feasibility and experience in the application of the existing “Stage 1" limit values.See Article 10 of Directive 99/30/EC.

[^c17958311]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" sales department either by telephone on 020-8996-9001 or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL.

[^c17958321]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" as for footnote (a) above.

[^c17958331]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" sales department either by telephone on 020-8996-9001 or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL.

[^c17958341]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" as for footnote (a) above.

[^c17958351]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" sales department either by telephone on 020-8996-9001 or by post from the BSI, Standards House, 389 Chiswick High Road, London W4 4AL.

[^c17958361]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" as for footnote (a) above.

[^c17958371]: OJ L378, 31.12.1982, p.15.

[^c17958381]: Copies of this International Standards Organisation publication can be purchased from the British Standards Institution “BSI" sales department either by telephone on 020-8996-9001 or by post from the BSI Standards House, 389 Chiswick High Road, London W4 4AL.

[^c17958391]: European Standards Institute “CEN" publication reference BSEN 12341, obtainable from the British Standards Institution “BSI" as for footnote (a) above.

[^key-f7d75a360db2b1bfe30aace0f9f5c82b]: Words in reg. 2 inserted (30.4.2005) by The Air Quality Limit Values (Wales) (Amendment) Regulations 2005 (S.I. 2005/1157), regs. 1(1), 3(1)

[^key-f93d763be0d98d0f2b97ea8cadcf03e2]: Words in reg. 8(6) inserted (30.4.2005) by The Air Quality Limit Values (Wales) (Amendment) Regulations 2005 (S.I. 2005/1157), regs. 1(1), 4

[^key-1bf57c00a8f51a577eb15cc9ef5a122d]: Reg. 10(12)-(14) inserted (30.4.2005) by The Air Quality Limit Values (Wales) (Amendment) Regulations 2005 (S.I. 2005/1157), regs. 1(1), 3(2)

[^key-97b9a501ffc82c6effa7fe8da5fce541]: Reg. 12(9) omitted (30.4.2005) by virtue of The Air Quality Limit Values (Wales) (Amendment) Regulations 2005 (S.I. 2005/1157), regs. 1(1), 3(3)

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