LegalizeRegulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance)
| Code | Prevention precautionary statements | Hazard class | Hazard category | Conditions for use | ||
|---|---|---|---|---|---|---|
| (1) | (2) | (3) | (4) | (5) | ||
| P201 | Obtain special instructions before use. | Explosives (section 2.1) | Unstable explosive | |||
| P201 | Obtain special instructions before use. | Germ cell mutagenicity (section 3.5) | 1A,1B, 2 | Consumer products – omit where P202 is used | ||
| P201 | Obtain special instructions before use. | Carcinogenicity (section 3.6) | 1A,1B, 2 | Consumer products – omit where P202 is used | ||
| P201 | Obtain special instructions before use. | Reproductive toxicity (section 3.7) | 1A,1B, 2 | Consumer products – omit where P202 is used | ||
| P201 | Obtain special instructions before use. | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | Consumer products – omit where P202 is used | ||
| P202 | Do not handle until all safety precautions have been read and understood. | Flammable gases (section 2.2) | A, B (chemically unstable gases) | |||
| P202 | Do not handle until all safety precautions have been read and understood. | Germ cell mutagenicity (section 3.5) | 1A,1B, 2 | |||
| P202 | Do not handle until all safety precautions have been read and understood. | Carcinogenicity (section 3.6) | 1A,1B, 2 | |||
| P202 | Do not handle until all safety precautions have been read and understood. | Reproductive toxicity (section 3.7) | 1A,1B, 2 | |||
| P202 | Do not handle until all safety precautions have been read and understood. | Reproductive toxicity, effects on or via lactation (section 3.7) | Additional category | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Explosives (section 2.1) | Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Flammable gases (section 2.2) | 1A, 1B, 2 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Aerosols (section 2.3) | 1, 2, 3 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Flammable liquids (section 2.6) | 1, 2, 3 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Flammable solids (section 2.7) | 1, 2 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Pyrophoric liquids (section 2.9) | 1 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Pyrophoric solids (section 2.10) | 1 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Oxidising liquids (section 2.13) | 1, 2, 3 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Oxidising solids (section 2.14) | 1, 2, 3 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Organic peroxides (section 2.15) | Types A, B, C, D, E, F | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
| P210 | Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. | |||||
| P211 | Do not spray on an open flame or other ignition source. | Aerosols (section 2.3) | 1, 2 | |||
| P212 | Avoid heating under confinement or reduction of the desensitising agent. | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
| P220 | Keep away from clothing and other combustible materials. | Oxidising gases (Section 2.4) | 1 | |||
| P220 | Keep away from clothing and other combustible materials. | Oxidising liquids (Section 2.13) | 1, 2, 3 | |||
| P220 | Keep away from clothing and other combustible materials. | Oxidising solids (Section 2.14) | 1, 2, 3 | |||
| P220 | Keep away from clothing and other combustible materials. | ————— | ————— | ————— | ————— | ————— |
| P220 | Keep away from clothing and other combustible materials. | |||||
| P222 | Do not allow contact with air. | Flammable gases (section 2.2) | Pyrophoric gas | — if emphasis of the hazard statement is deemed necessary. | ||
| P222 | Do not allow contact with air. | Pyrophoric liquids (section 2.9) | 1 | — if emphasis of the hazard statement is deemed necessary. | ||
| P222 | Do not allow contact with air. | Pyrophoric solids (section 2.10) | 1 | |||
| P222 | Do not allow contact with air. | |||||
| P223 | Do not allow contact with water. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2 | — if emphasis of the hazard statement is deemed necessary | — if emphasis of the hazard statement is deemed necessary. | |
| — if emphasis of the hazard statement is deemed necessary. | ||||||
| P230 | Keep wetted with … | Explosives (section 2.1) | Divisions 1.1, 1.2, 1.3, 1.5 | Manufacturer/supplier to specify appropriate material — for substances and mixtures which are wetted, diluted, dissolved or suspended with a phlegmatiser in order to suppress their explosive properties | ||
| P230 | Keep wetted with … | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | Manufacturer/supplier to specify appropriate material | ||
| P230 | Keep wetted with … | |||||
| P231 | Handle and store contents under inert gas/… | Pyrophoric liquids (Section 2.9) | 1 | … Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate. | ||
| P231 | Handle and store contents under inert gas/… | Pyrophoric solids (Section 2.10) | 1 | … Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate. | ||
| P231 | Handle and store contents under inert gas/… | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | — if the substance or mixture reacts readily with moisture in air. … Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate. | ||
| P231 | Handle and store contents under inert gas/… | |||||
| P232 | Protect from moisture. | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |||
| P233 | Keep container tightly closed. | Flammable liquids (section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere | ||
| P233 | Keep container tightly closed. | Pyrophoric liquids (section 2.9) | 1 | |||
| P233 | Keep container tightly closed. | Pyrophoric solids (section 2.10) | 1 | |||
| P233 | Keep container tightly closed. | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
| P233 | Keep container tightly closed. | Acute toxicity – inhalation (section 3.1) | 1, 2, 3 | — if the chemical is volatile and may generate a hazardous atmosphere | ||
| P233 | Keep container tightly closed. | Specific target organ toxicity – single exposure; respiratory tract irritation (section 3.8) | 3 | — if the chemical is volatile and may generate a hazardous atmosphere | ||
| P233 | Keep container tightly closed. | Specific target organ toxicity – single exposure; narcotic effects (section 3.8) | 3 | — if the chemical is volatile and may generate a hazardous atmosphere | ||
| P233 | Keep container tightly closed. | |||||
| P234 | Keep only in original packaging. | Explosives (Section 2.1) | Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if the chemical is volatile and may generate a hazardous atmosphere | ||
| P234 | Keep only in original packaging. | Self-reactive substances and mixtures (Section 2.8) | Types A, B, C, D, E, F | |||
| P234 | Keep only in original packaging. | Organic peroxides (Section 2.15) | Types A, B, C, D, E, F | |||
| P234 | Keep only in original packaging. | Corrosive to metals (Section 2.16) | 1 | |||
| P235 | Keep cool. | Flammable liquids (Section 2.6) | 1, 2, 3 | — for flammable liquids category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere | ||
| P235 | Keep cool. | Self-reactive substances and mixtures (Section 2.8) | Types A, B, C, D, E, F | — may be omitted if P411 is given on the label | ||
| P235 | Keep cool. | Self-heating substances and mixtures (Section 2.11) | 1, 2 | — may be omitted if P413 is given on the label | ||
| P235 | Keep cool. | Organic peroxides (Section 2.15) | Types A, B, C, D, E, F | — may be omitted if P411 is given on the label | ||
| P240 | Ground and bond container and receiving equipment. | Explosives (Section 2.1) | Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if the explosive is electrostatically sensitive | ||
| P240 | Ground and bond container and receiving equipment. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere | ||
| P240 | Ground and bond container and receiving equipment. | Flammable solids (Section 2.7) | 1, 2 | — if the solid is electrostatically sensitive | ||
| P240 | Ground and bond container and receiving equipment. | Self-reactive substances and mixtures (Section 2.8) | Types A,B,C, D, E, F | — if electrostatically sensitive and able to generate an explosive atmosphere | ||
| P240 | Ground and bond container and receiving equipment. | Organic peroxides (Section 2.15) | Types A,B,C, D, E, F | — if electrostatically sensitive and able to generate an explosive atmosphere | ||
| P241 | Use explosion-proof [electrical/ventilating/lighting/…] equipment. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere. — text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate. | ||
| P241 | Use explosion-proof [electrical/ventilating/lighting/…] equipment. | Flammable solids (Section 2.7) | 1, 2 | — if dust clouds can occur. — text in square brackets may be used to specify specific electrical, ventilating, lighting or other equipment if necessary and as appropriate. | ||
| P242 | Use non-sparking tools. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere and if the minimum ignition energy is very low. (This applies to substances and mixtures where the ignition energy is < 0,1 mJ, e.g. carbon disulphide). | ||
| P243 | Take action to prevent static discharges. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if the liquid is volatile and may generate an explosive atmosphere. | ||
| P244 | Keep valves and fittings free from oil and grease. | Oxidising gases (section 2.4) | 1 | |||
| P250 | Do not subject to grinding/shock/friction … | Explosives (Section 2.1) | Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if the explosive is mechanically sensitive … Manufacturer/supplier to specify applicable rough handling. | ||
| P251 | Do not pierce or burn, even after use. | Aerosols (section 2.3) | 1, 2, 3 | |||
| P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | Acute toxicity — inhalation (section 3.1) | 1, 2 | Manufacturer/supplier to specify applicable conditions. | ||
| P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | Manufacturer/supplier to specify applicable conditions. | ||
| P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | Specific target organ toxicity — repeated exposure (section 3.9) | 1, 2 | Manufacturer/supplier to specify applicable conditions. | ||
| P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | Skin corrosion (section 3.2) | 1A, 1B, 1C | — Specify do not breathe dusts or mists. — if inhalable particles of dusts or mists may occur during use. | ||
| P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | — Specify do not breathe dusts or mists. — if inhalable particles of dusts or mists may occur during use. | ||
| P260 | Do not breathe dust/fume/gas/mist/vapours/spray. | |||||
| P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | Acute toxicity — inhalation (Section 3.1) | 3, 4 | — Specify do not breathe dusts or mists. — if inhalable particles of dusts or mists may occur during use. | — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. | |
| P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | Respiratory sensitisation (Section 3.4) | 1, 1A, 1B | |||
| P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | Skin sensitisation (Section 3.4) | 1, 1A, 1B | |||
| P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) | 3 | |||
| P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) | 3 | |||
| P261 | Avoid breathing dust/fume/gas/mist/vapours/spray. | |||||
| P262 | Do not get in eyes, on skin, or on clothing. | Acute toxicity — dermal (section 3.1) | 1, 2 | — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. | ||
| — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. | ||||||
| P263 | Avoid contact during pregnancy and while nursing. | Reproductive toxicity — effects on or via lactation (Section 3.7) | Additional category | — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. | ||
| — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. | ||||||
| P264 | Wash … thoroughly after handling. | Acute toxicity — oral (section 3.1) | 1, 2, 3, 4 | Manufacturer/supplier to specify parts of the body to be washed after handling. | — may be omitted if P260 is given on the label Manufacturer/supplier to specify applicable conditions. | |
| P264 | Wash … thoroughly after handling. | Acute toxicity — dermal (section 3.1) | 1, 2 | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P264 | Wash … thoroughly after handling. | Skin corrosion (section 3.2) | 1A, 1B, 1C | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P264 | Wash … thoroughly after handling. | Skin irritation (section 3.2) | 2 | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P264 | Wash … thoroughly after handling. | Eye irritation (section 3.3) | 2 | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P264 | Wash … thoroughly after handling. | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P264 | Wash … thoroughly after handling. | Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P264 | Wash … thoroughly after handling. | Specific target organ toxicity — repeated exposure (section 3.9) | 1 | Manufacturer/supplier to specify parts of the body to be washed after handling. | ||
| P270 | Do not eat, drink or smoke when using this product. | Acute toxicity — oral (section 3.1) | 1, 2, 3, 4 | |||
| P270 | Do not eat, drink or smoke when using this product. | Acute toxicity — dermal (section 3.1) | 1, 2 | |||
| P270 | Do not eat, drink or smoke when using this product. | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
| P270 | Do not eat, drink or smoke when using this product. | Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | |||
| P270 | Do not eat, drink or smoke when using this product. | Specific target organ toxicity — repeated exposure (section 3.9) | 1 | |||
| P271 | Use only outdoors or in a well-ventilated area. | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |||
| P271 | Use only outdoors or in a well-ventilated area. | Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
| P271 | Use only outdoors or in a well-ventilated area. | Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3 | |||
| P271 | Use only outdoors or in a well-ventilated area. | |||||
| P272 | Contaminated work clothing should not be allowed out of the workplace. | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P273 | Avoid release to the environment. | Hazardous to the aquatic environment — acute aquatic hazard (section 4.1) | 1 | — if this is not the intended use. | ||
| P273 | Avoid release to the environment. | Hazardous to the aquatic environment — long-term aquatic hazard (section 4.1) | 1, 2, 3, 4 | — if this is not the intended use. | ||
| P273 | Avoid release to the environment. | ————— | ————— | ————— | ————— | ————— |
| P273 | Avoid release to the environment. | |||||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Explosives (section 2.1) | Unstable explosive and divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if this is not the intended use. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Flammable gases (section 2.2) | Pyrophoric gas | — if this is not the intended use. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Flammable liquids (section 2.6) | 1, 2, 3 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Flammable solids (section 2.7) | 1, 2 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Pyrophoric liquids (section 2.9) | 1 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Pyrophoric solids (section 2.10) | 1 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Self-heating substances and mixtures (section 2.11) | 1, 2 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Oxidizing liquids (section 2.13) | 1, 2, 3 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Oxidizing solids (section 2.14) | 1, 2, 3 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Organic peroxides (section 2.15) | Types A, B, C, D, E, F | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Acute toxicity – dermal (section 3.1) | 1, 2, 3, 4 | — Specify protective gloves/clothing. Manufacturer/supplier may further specify type of equipment where appropriate. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Skin corrosion (section 3.2) | 1A, 1B, 1C | — Specify protective gloves/clothing and eye/face protection. Manufacturer/supplier may further specify type of equipment where appropriate. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Skin irritation (section 3.2) | 2 | — Specify protective gloves. Manufacturer/supplier may further specify type of equipment where appropriate. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Skin sensitisation (section 3.4) | 1, 1A, 1B | — Specify protective gloves. Manufacturer/supplier may further specify type of equipment where appropriate. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Serious eye damage (section 3.3) | 1 | — Specify eye/face protection. Manufacturer/supplier may further specify type of equipment where appropriate. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Eye irritation (section 3.3) | 2 | — Specify eye/face protection. Manufacturer/supplier may further specify type of equipment where appropriate. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Carcinogenicity (section 3.6) | 1A, 1B, 2 | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | Reproductive toxicity (section 3.7) | 1A, 1B, 2 | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | ————— | ————— | ————— | ————— | ————— |
| P280 | Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/… | |||||
| P282 | Wear cold insulating gloves and either face shield or eye protection. | Gases under pressure (Section 2.5) | Refrigerated liquefied gas | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P283 | Wear fire resistant or flame retardant clothing. | Oxidising liquids (Section 2.13) | 1 | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | Manufacturer/supplier to specify the appropriate type of personal protective equipment. | |
| P283 | Wear fire resistant or flame retardant clothing. | Oxidising solids (Section 2.14) | 1 | |||
| P284 | [In case of inadequate ventilation] wear respiratory protection. | Acute toxicity — inhalation (Section 3.1) | 1, 2 | — text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use. Manufacturer/supplier to specify equipment. | ||
| P284 | [In case of inadequate ventilation] wear respiratory protection. | Respiratory sensitisation (Section 3.4) | 1, 1A, 1B | — text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use. Manufacturer/supplier to specify equipment. | ||
| P284 | [In case of inadequate ventilation] wear respiratory protection. | ————— | ————— | ————— | ————— | ————— |
| P284 | [In case of inadequate ventilation] wear respiratory protection. | |||||
| P231 + P232 | Handle and store contents under inert gas/… Protect from moisture. | Pyrophoric liquids (Section 2.9) | 1 | — text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use. Manufacturer/supplier to specify equipment. | … Manufacturer/supplier to specify the appropriate liquid or gas if ‘inert gas’ is not appropriate. | |
| P231 + P232 | Handle and store contents under inert gas/… Protect from moisture. | Pyrophoric solids (Section 2.10) | 1 | — text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use. Manufacturer/supplier to specify equipment. | … Manufacturer/supplier to specify the appropriate liquid or gas if ‘inert gas’ is not appropriate. | |
| P231 + P232 | Handle and store contents under inert gas/… Protect from moisture. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | — if the substance or mixture reacts readily with moisture in air. … Manufacturer/supplier to specify appropriate liquid or gas if ‘inert gas’ is not appropriate. | ||
| P231 + P232 | Handle and store contents under inert gas/… Protect from moisture. | ————— | ————— | ————— | ————— | ————— |
| P231 + P232 | Handle and store contents under inert gas/… Protect from moisture. |
Table 6.3
Precautionary statements — Response
| Code | Response precautionary statements | Hazard class | Hazard category | Conditions for use | ||
|---|---|---|---|---|---|---|
| (1) | (2) | (3) | (4) | (5) | ||
| P301 | IF SWALLOWED: | Acute toxicity – oral (section 3.1) | 1, 2, 3, 4 | |||
| P301 | IF SWALLOWED: | Skin corrosion (section 3.2) | 1, 1A, 1B, 1C | |||
| P301 | IF SWALLOWED: | Aspiration Hazard (section 3.10) | 1 | |||
| P302 | IF ON SKIN: | Pyrophoric liquids (section 2.9) | 1 | |||
| P302 | IF ON SKIN: | Pyrophoric solids (section 2.10) | 1 | |||
| P302 | IF ON SKIN: | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2 | |||
| P302 | IF ON SKIN: | Acute toxicity – dermal (section 3.1) | 1, 2, 3, 4 | |||
| P302 | IF ON SKIN: | Skin irritation (section 3.2) | 2 | |||
| P302 | IF ON SKIN: | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P302 | IF ON SKIN: | |||||
| P303 | IF ON SKIN (or hair): | Flammable liquids (section 2.6) | 1, 2, 3 | |||
| P303 | IF ON SKIN (or hair): | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P303 | IF ON SKIN (or hair): | |||||
| P304 | IF INHALED: | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |||
| P304 | IF INHALED: | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P304 | IF INHALED: | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
| P304 | IF INHALED: | Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
| P304 | IF INHALED: | Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3 | |||
| P304 | IF INHALED: | |||||
| P305 | IF IN EYES: | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P305 | IF IN EYES: | Serious eye damage/eye irritation (section 3.3) | 1 | |||
| P305 | IF IN EYES: | Eye irritation (section 3.3) | 2 | |||
| P306 | IF ON CLOTHING: | Oxidising liquids (section 2.13) | 1 | |||
| P306 | IF ON CLOTHING: | Oxidising solids (section 2.14) | 1 | |||
| P306 | IF ON CLOTHING: | ————— | ————— | ————— | ————— | ————— |
| P306 | IF ON CLOTHING: | |||||
| P308 | IF exposed or concerned: | Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |||
| P308 | IF exposed or concerned: | Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
| P308 | IF exposed or concerned: | Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
| P308 | IF exposed or concerned: | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
| P308 | IF exposed or concerned: | Specific target organ toxicity, single exposure (section 3.8) | 1, 2 | |||
| P308 | IF exposed or concerned: | ————— | ————— | ————— | ————— | ————— |
| P308 | IF exposed or concerned: | |||||
| P310 | Immediately call a POISON CENTER/doctor/… | Acute toxicity — oral (section 3.1) | 1, 2, 3 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P310 | Immediately call a POISON CENTER/doctor/… | Acute toxicity — dermal (section 3.1) | 1, 2 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P310 | Immediately call a POISON CENTER/doctor/… | Acute toxicity — inhalation (section 3.1) | 1, 2 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P310 | Immediately call a POISON CENTER/doctor/… | Skin corrosion (section 3.2) | 1A, 1B, 1C | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P310 | Immediately call a POISON CENTER/doctor/… | Serious eye damage/eye irritation (section 3.3) | 1 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P310 | Immediately call a POISON CENTER/doctor/… | Aspiration hazard (section 3.10) | 1 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P311 | Call a POISON CENTER/doctor/… | Acute toxicity — inhalation (section 3.1) | 3 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P311 | Call a POISON CENTER/doctor/… | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P311 | Call a POISON CENTER/doctor/… | Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P311 | Call a POISON CENTER/doctor/… | |||||
| P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | Acute toxicity — oral (Section 3.1) | 4 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. | |
| P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | Acute toxicity — dermal (Section 3.1) | 3, 4 | |||
| P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | Acute toxicity — inhalation (Section 3.1) | 4 | |||
| P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | Specific target organ toxicity — single exposure; respiratory tract irritation (Section 3.8) | 3 | |||
| P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | Specific target organ toxicity — single exposure; narcotic effects (Section 3.8) | 3 | |||
| P312 | Call a POISON CENTRE/doctor/… if you feel unwell. | |||||
| P313 | Get medical advice/attention. | Skin irritation (section 3.2) | 2, 3 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P313 | Get medical advice/attention. | Eye irritation (section 3.3) | 2 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P313 | Get medical advice/attention. | Skin sensitisation (section 3.4) | 1, 1A, 1B | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P313 | Get medical advice/attention. | Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P313 | Get medical advice/attention. | Carcinogenicity (section 3.6) | 1A, 1B, 2 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P313 | Get medical advice/attention. | Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
| P313 | Get medical advice/attention. | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
| P313 | Get medical advice/attention. | |||||
| P314 | Get medical advice/attention if you feel unwell. | Specific target organ toxicity — repeated exposure (section 3.9) | 1, 2 | |||
| P315 | Get immediate medical advice/attention. | Gases under pressure (section 2.5) | Refrigerated liquefied gas | |||
| P320 | Specific treatment is urgent (see … on this label). | Acute toxicity — inhalation (Section 3.1) | 1, 2 | — if immediate administration of antidote is required. … Reference to supplemental first aid instruction. | ||
| P321 | Specific treatment (see … on this label). | Acute toxicity — oral (Section 3.1) | 1, 2, 3 | — if immediate administration of antidote is required. … Reference to supplemental first aid instruction. | ||
| P321 | Specific treatment (see … on this label). | Acute toxicity, dermal (Section 3.1) | 1, 2, 3, 4 | — if immediate measures such as specific cleansing agent are advised. … Reference to supplemental first aid instruction. | ||
| P321 | Specific treatment (see … on this label). | Acute toxicity — inhalation (Section 3.1) | 3 | — if immediate specific measures are required. … Reference to supplemental first aid instruction. | ||
| P321 | Specific treatment (see … on this label). | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | … Reference to supplemental first aid instruction. Manufacturer/supplier may specify a cleansing agent if appropriate. | ||
| P321 | Specific treatment (see … on this label). | Skin irritation (Section 3.2) | 2 | … Reference to supplemental first aid instruction. Manufacturer/supplier may specify a cleansing agent if appropriate. | ||
| P321 | Specific treatment (see … on this label). | Skin sensitisation (Section 3.4) | 1, 1A, 1B | … Reference to supplemental first aid instruction. Manufacturer/supplier may specify a cleansing agent if appropriate. | ||
| P321 | Specific treatment (see … on this label). | Specific target organ toxicity — single exposure (Section 3.8) | 1 | — if immediate measures are required. … Reference to supplemental first aid instruction. | ||
| P321 | Specific treatment (see … on this label). | ————— | ————— | ————— | ————— | ————— |
| P321 | Specific treatment (see … on this label). | |||||
| P330 | Rinse mouth. | Acute toxicity — oral (section 3.1) | 1, 2, 3, 4 | |||
| P330 | Rinse mouth. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P331 | Do NOT induce vomiting. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P331 | Do NOT induce vomiting. | Aspiration hazard (section 3.10) | 1 | |||
| P331 | Do NOT induce vomiting. | |||||
| P332 | If skin irritation occurs: | Skin irritation (section 3.2) | 2 | may be omitted if P333 is given on the label. | ||
| P333 | If skin irritation or rash occurs: | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P334 | Immerse in cool water [or wrap in wet bandages]. | Pyrophoric liquids (Section 2.9) | 1 | — text in square brackets to be used for pyrophoric liquids and solids | ||
| P334 | Immerse in cool water [or wrap in wet bandages]. | Pyrophoric solids (Section 2.10) | 1 | — text in square brackets to be used for pyrophoric liquids and solids | ||
| P334 | Immerse in cool water [or wrap in wet bandages]. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2 | Use only ‘immerse in cool water.’ Text in square brackets should not be used. | ||
| P334 | Immerse in cool water [or wrap in wet bandages]. | |||||
| P335 | Brush off loose particles from skin. | Pyrophoric solids (section 2.10) | 1 | |||
| P335 | Brush off loose particles from skin. | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2 | |||
| P336 | Thaw frosted parts with lukewarm water. Do not rub affected area. | Gases under pressure (section 2.5) | Refrigerated liquefied gas | |||
| P337 | If eye irritation persists: | Eye irritation (section 3.3) | 2 | |||
| P338 | Remove contact lenses, if present and easy to do. Continue rinsing. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P338 | Remove contact lenses, if present and easy to do. Continue rinsing. | Serious eye damage/eye irritation (section 3.3) | 1 | |||
| P338 | Remove contact lenses, if present and easy to do. Continue rinsing. | Eye irritation (section 3.3) | 2 | |||
| P338 | Remove contact lenses, if present and easy to do. Continue rinsing. | |||||
| P340 | Remove person to fresh air and keep comfortable for breathing. | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | |||
| P340 | Remove person to fresh air and keep comfortable for breathing. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P340 | Remove person to fresh air and keep comfortable for breathing. | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
| P340 | Remove person to fresh air and keep comfortable for breathing. | Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
| P340 | Remove person to fresh air and keep comfortable for breathing. | Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3 | |||
| P340 | Remove person to fresh air and keep comfortable for breathing. | ————— | ————— | ————— | ————— | ————— |
| P340 | Remove person to fresh air and keep comfortable for breathing. | |||||
| P342 | If experiencing respiratory symptoms: | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
| ————— | ————— | ————— | ————— | ————— | ||
| P351 | Rinse cautiously with water for several minutes. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P351 | Rinse cautiously with water for several minutes. | Serious eye damage/eye irritation (section 3.3) | 1 | |||
| P351 | Rinse cautiously with water for several minutes. | Eye irritation (section 3.3) | 2 | |||
| P351 | Rinse cautiously with water for several minutes. | |||||
| P352 | Wash with plenty of water/… | Acute toxicity — dermal (section 3.1) | 1, 2, 3, 4 | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | ||
| P352 | Wash with plenty of water/… | Skin irritation (section 3.2) | 2 | |||
| P352 | Wash with plenty of water/… | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P352 | Wash with plenty of water/… | |||||
| P353 | Rinse skin with water [or shower]. | Flammable liquids (Section 2.6) | 1, 2, 3 | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | |
| P353 | Rinse skin with water [or shower]. | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | |
| P353 | Rinse skin with water [or shower]. | |||||
| P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | Oxidising liquids (section 2.13) | 1 | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | |
| P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | Oxidising solids (section 2.14) | 1 | |||
| P360 | Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | |||||
| P361 | Take off immediately all contaminated clothing. | Flammable liquids (section 2.6) | 1, 2, 3 | |||
| P361 | Take off immediately all contaminated clothing. | Acute toxicity — dermal (section 3.1) | 1, 2, 3 | |||
| P361 | Take off immediately all contaminated clothing. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P362 | Take off contaminated clothing. | Acute toxicity, dermal (section 3.1) | 4 | |||
| P362 | Take off contaminated clothing. | Skin irritation (section 3.2) | 2 | |||
| P362 | Take off contaminated clothing. | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P363 | Wash contaminated clothing before reuse. | Skin corrosion (section 3.2) | 1A, 1B, 1C | |||
| P364 | And wash it before reuse. | Acute toxicity, dermal (section 3.1) | 1, 2, 3, 4 | |||
| P364 | And wash it before reuse. | Skin irritation (section 3.2) | 2 | |||
| P364 | And wash it before reuse. | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P364 | And wash it before reuse. | |||||
| P370 | In case of fire: | Explosives (section 2.1) | Unstable explosives and divisions 1.1, 1.2, 1.3, 1.4, 1.5 | |||
| P370 | In case of fire: | Oxidising gases (section 2.4) | 1 | |||
| P370 | In case of fire: | Flammable liquids (section 2.6) | 1, 2, 3 | |||
| P370 | In case of fire: | Flammable solids (section 2.7) | 1, 2 | |||
| P370 | In case of fire: | Self-reactive substances and mixtures (section 2.8) | Types A, B, C, D, E, F | |||
| P370 | In case of fire: | Pyrophoric liquids (section 2.9) | 1 | |||
| P370 | In case of fire: | Pyrophoric solids (section 2.10) | 1 | |||
| P370 | In case of fire: | Substances and mixtures which, in contact with water, emit flammable gases (section 2.12) | 1, 2, 3 | |||
| P370 | In case of fire: | Oxidising liquids (section 2.13) | 1, 2, 3 | |||
| P370 | In case of fire: | Oxidising solids (section 2.14) | 1, 2, 3 | |||
| P370 | In case of fire: | Organic Peroxides (section 2.15) | Types A, B, C, D, E, F | |||
| P370 | In case of fire: | Desensitised explosives (section 2.17) | 1, 2, 3 | |||
| P371 | In case of major fire and large quantities: | Oxidising liquids (section 2.13) | 1 | |||
| P371 | In case of major fire and large quantities: | Oxidising solids (section 2.14) | 1 | |||
| P371 | In case of major fire and large quantities: | Desensitised explosives (section 2.17) | 4 | |||
| P371 | In case of major fire and large quantities: | |||||
| P372 | Explosion risk. | Explosives (Section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, and 1.5 | |||
| P372 | Explosion risk. | Explosives (Section 2.1) | Division 1.4 | — except for explosives of division 1.4 (compatibility group S) in transport packaging. | ||
| P372 | Explosion risk. | Self-reactive substances and mixtures (Section 2.8) | Type A | |||
| P372 | Explosion risk. | Organic peroxides (Section 2.15) | Type A | |||
| P373 | DO NOT fight fire when fire reaches explosives. | Explosives (Section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.5 | |||
| P373 | DO NOT fight fire when fire reaches explosives. | Explosives (Section 2.1) | Division 1.4 | — except for explosives of division 1.4 (compatibility group S) in transport packaging. | ||
| P373 | DO NOT fight fire when fire reaches explosives. | Self-reactive substances and mixtures (Section 2.8) | Type A | |||
| P373 | DO NOT fight fire when fire reaches explosives. | Organic peroxides (Section 2.15) | Type A | |||
| P373 | DO NOT fight fire when fire reaches explosives. | ————— | ————— | ————— | ————— | ————— |
| P373 | DO NOT fight fire when fire reaches explosives. | |||||
| P375 | Fight fire remotely due to the risk of explosion. | Explosives (section 2.1) | Division 1.4 | — for explosives of division 1.4 (compatibility group S) in transport packaging. | ||
| P375 | Fight fire remotely due to the risk of explosion. | Self-reactive substances and mixtures (section 2.8) | Type B | |||
| P375 | Fight fire remotely due to the risk of explosion. | Oxidising liquids (section 2.13) | 1 | |||
| P375 | Fight fire remotely due to the risk of explosion. | Oxidising solids (section 2.14) | 1 | |||
| P375 | Fight fire remotely due to the risk of explosion. | Organic peroxides (section 2.15) | Type B | |||
| P375 | Fight fire remotely due to the risk of explosion. | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
| P375 | Fight fire remotely due to the risk of explosion. | |||||
| P376 | Stop leak if safe to do so. | Oxidising gases (section 2.4) | 1 | |||
| P377 | Leaking gas fire: Do not extinguish, unless leak can be stopped safely. | Flammable gases (section 2.2) | 1A, 1B, 2 | |||
| P378 | Use … to extinguish. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Flammable solids (Section 2.7) | 1, 2 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Self-reactive substances and mixtures (Section 2.8) | Types B, C, D, E, F | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Pyrophoric liquids (Section 2.9) | 1 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Pyrophoric solids (Section 2.10) | 1 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Oxidising liquids (Section 2.13) | 1, 2, 3 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Oxidising solids (Section 2.14) | 1, 2, 3 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | Organic peroxides (Section 2.15) | Types B, C, D, E, F | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P378 | Use … to extinguish. | |||||
| P380 | Evacuate area. | Explosives (section 2.1) | Unstable explosives and Divisions 1.1, 1.2, 1.3, 1.4, 1.5 | — if water increases risk … Manufacturer/supplier to specify appropriate media | ||
| P380 | Evacuate area. | Self-reactive substances and mixtures (section 2.8) | Types A, B | |||
| P380 | Evacuate area. | Oxidising liquids (section 2.13) | 1 | |||
| P380 | Evacuate area. | Oxidising solids (section 2.14) | 1 | |||
| P380 | Evacuate area. | Organic peroxides (section 2.15) | Types A, B | |||
| P380 | Evacuate area. | Desensitised explosives (section 2.17) | 1, 2, 3, 4 | |||
| P381 | In case of leakage, eliminate all ignition sources | Flammable gases (section 2.2) | 1A, 1B, 2 | |||
| P390 | Absorb spillage to prevent material damage. | Corrosive to metals (section 2.16) | 1 | |||
| P391 | Collect spillage. | Hazardous to the aquatic environment – acute aquatic hazard (section 4.1) | 1 | |||
| P391 | Collect spillage. | Hazardous to the aquatic environment – long-term aquatic hazard (section 4.1) | 1, 2 | |||
| P391 | Collect spillage. | |||||
| P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER/doctor/… | Acute toxicity — oral (section 3.1) | 1, 2, 3 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER/doctor/… | Aspiration hazard (section 3.10) | 1 | |||
| P301 + P310 | IF SWALLOWED: Immediately call a POISON CENTER/doctor/… | |||||
| P301 + P312 | IF SWALLOWED: Call a POISON CENTER/doctor/… if you feel unwell | Acute toxicity – oral (section 3.1) | 4 | … Manufacturer/supplier to specify the appropriate source of emergency medical advice | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | |
| ————— | ————— | ————— | ————— | ————— | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | |
| P302 + P334 | IF ON SKIN: Immerse in cool water or wrap in wet bandages. | Pyrophoric liquids (Section 2.9) | 1 | |||
| ————— | ————— | ————— | ————— | ————— | ||
| P302 + P352 | IF ON SKIN: Wash with plenty of water/… | Acute toxicity — dermal (section 3.1) | 1, 2, 3, 4 | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | ||
| P302 + P352 | IF ON SKIN: Wash with plenty of water/… | Skin irritation (section 3.2) | 2 | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | ||
| P302 + P352 | IF ON SKIN: Wash with plenty of water/… | Skin sensitisation (section 3.4) | 1, 1A, 1B | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | ||
| P302 + P352 | IF ON SKIN: Wash with plenty of water/… | ————— | ————— | ————— | ————— | ————— |
| P302 + P352 | IF ON SKIN: Wash with plenty of water/… | |||||
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | Acute toxicity — inhalation (section 3.1) | 1, 2, 3, 4 | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | ||
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | Skin corrosion (section 3.2) | 1A, 1B, 1C | …Manufacturer/supplier may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. | ||
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | |||
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | Specific target organ toxicity — single exposure; respiratory tract irritation (section 3.8) | 3 | |||
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | Specific target organ toxicity — single exposure; narcosis (section 3.8) | 3 | |||
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | ————— | ————— | ————— | ————— | ————— |
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | ————— | ————— | ————— | ————— | ————— |
| P304 + P340 | IF INHALED: Remove person to fresh air and keep comfortable for breathing. | |||||
| P306 + P360 | IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | Oxidising liquids (section 2.13) | 1 | |||
| P306 + P360 | IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | Oxidising solids (section 2.14) | 1 | |||
| P306 + P360 | IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. | |||||
| P308 + P311 | IF exposed or concerned: Call a POISON CENTER/doctor/… | Specific target organ toxicity — single exposure (section 3.8) | 1, 2 | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P308 + P313 | IF exposed or concerned: Get medical advice/attention. | Germ cell mutagenicity (section 3.5) | 1A, 1B, 2 | |||
| P308 + P313 | IF exposed or concerned: Get medical advice/attention. | Carcinogenicity (section 3.6) | 1A, 1B, 2 | |||
| P308 + P313 | IF exposed or concerned: Get medical advice/attention. | Reproductive toxicity (section 3.7) | 1A, 1B, 2 | |||
| P308 + P313 | IF exposed or concerned: Get medical advice/attention. | Reproductive toxicity — effects on or via lactation (section 3.7) | Additional category | |||
| P308 + P313 | IF exposed or concerned: Get medical advice/attention. | ————— | ————— | ————— | ————— | ————— |
| P308 + P313 | IF exposed or concerned: Get medical advice/attention. | |||||
| P332 + P313 | If skin irritation occurs: Get medical advice/attention. | Skin irritation (Section 3.2) | 2 | — may be omitted when P333 + P313 is given on the label. | ||
| P333 + P313 | If skin irritation or rash occurs: Get medical advice/attention. | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P336 + P315 | Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention. | Gases under pressure (Section 2.5) | Refrigerated liquefied gas | |||
| ————— | ————— | ————— | ————— | ————— | ||
| P337 + P313 | If eye irritation persists: Get medical advice/attention. | Eye irritation (section 3.3) | 2 | |||
| P342 + P311 | If experiencing respiratory symptoms: Call a POISON CENTER/doctor/… | Respiratory sensitisation (section 3.4) | 1, 1A, 1B | …Manufacturer/supplier to specify the appropriate source of emergency medical advice. | ||
| P361 + P364 | Take off immediately all contaminated clothing and wash it before reuse. | Acute toxicity, dermal (section 3.1) | 1, 2, 3 | |||
| P362 + P364 | Take off contaminated clothing and wash it before reuse. | Acute toxicity, dermal (section 3.1) | 4 | |||
| P362 + P364 | Take off contaminated clothing and wash it before reuse. | Skin irritation (section 3.2) | 2 | |||
| P362 + P364 | Take off contaminated clothing and wash it before reuse. | Skin sensitisation (section 3.4) | 1, 1A, 1B | |||
| P362 + P364 | Take off contaminated clothing and wash it before reuse. | |||||
| P370 + P376 | In case of fire: Stop leak if safe to do so. | Oxidizing gases (section 2.4) | 1 | |||
| P370 + P378 | In case of fire: Use … to extinguish. | Flammable liquids (Section 2.6) | 1, 2, 3 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Flammable solids (Section 2.7) | 1, 2 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Self-reactive substances and mixtures (Section 2.8) | Types C, D, E, F | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Pyrophoric liquids (Section 2.9) | 1 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Pyrophoric solids (Section 2.10) | 1 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2, 3 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Oxidising liquids (Section 2.13) | 1, 2, 3 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Oxidising solids (Section 2.14) | 1, 2, 3 | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | Organic peroxides (Section 2.15) | Types C, D, E, F | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P370 + P378 | In case of fire: Use … to extinguish. | |||||
| P301 + P330 + P331 | IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | — if water increases risk. … Manufacturer/sup-plier to specify appropriate media. | ||
| P302 + P335 + P334 | IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. | Pyrophoric solids (Section 2.10) | 1 | — text in square brackets to be used for pyrophoric solids | ||
| P302 + P335 + P334 | IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages]. | Substances and mixtures which, in contact with water, emit flammable gases (Section 2.12) | 1, 2 | — use only ‘Immerse in cold water’. Text in square brackets should not be used. | ||
| P303 + P361 + P353 | IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. | Flammable liquids (Section 2.6) | 1, 2, 3 | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. | ||
| P303 + P361 + P353 | IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | — text in square brackets to be included where the manufacturer/supplier considers it appropriate for the specific chemical. | ||
| P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. | Skin corrosion (Section 3.2) | 1, 1A, 1B, 1C | |||
| P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. | Serious eye damage/eye irritation (Section 3.3) | 1 | |||
| P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. | Eye irritation (Section 3.3) | 2 | |||
| P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. | ————— | ————— | ————— | ————— | ————— |
| P305 + P351 + P338 | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. | |||||
| P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. | Explosives (section 2.1) | Division 1.4 | — for explosives of division 1.4 (compatibility group S) in transport packaging | ||
| P370 + P380 + P375 | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. | Desensitised explosives (section 2.17) | 1, 2, 3 | |||
| P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. | Oxidising liquids (section 2.13) | 1 | |||
| P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. | Oxidising solids (section 2.14) | 1 | |||
| P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. | Desensitised explosives (section 2.17) | 4 | |||
| P371 + P380 + P375 | In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. | |||||
| P370 + P372 + P380 + P373 | In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives | Explosives (Section 2.1) | Unstable explosives and divisions 1.1, 1.2, 1.3, 1.5 | |||
| P370 + P372 + P380 + P373 | In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives | Explosives (Section 2.1) | Division 1.4 | — except for explosives of division 1.4 (compatibility group S) in transport packaging. | ||
| P370 + P372 + P380 + P373 | In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives | Self-reactive substances and mixtures (Section 2.8) | Type A | |||
| P370 + P372 + P380 + P373 | In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives | Organic peroxides (Section 2.15) | Type A | |||
| P370 + P380 + P375 + [P378] | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish]. | Self-reactive substances and mixtures (Section 2.8) | Type B | — text in square brackets to be used if water increases risk. … Manufacturer/supplier to specify appropriate media. | ||
| P370 + P380 + P375 + [P378] | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish]. | Organic peroxides (Section 2.15) | Type B | — text in square brackets to be used if water increases risk. … Manufacturer/supplier to specify appropriate media. | ||
| P370 + P380 + P375 + [P378] | In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use … to extinguish]. |
Table 6.4
Precautionary statements — Storage
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